期刊
MATERIALS
卷 3, 期 2, 页码 841-862出版社
MDPI
DOI: 10.3390/ma3020841
关键词
lanthanide; nitrogen reduction; nitrogen fixation; organolanthanide; imide; dinitrogen complexes; azobenzene reduction
This paper reviews the current array of complexes of relevance to achieving lanthanide mediated nitrogen fixation. A brief history of nitrogen fixation is described, including a limited discussion of successful transition metal facilitated nitrogen fixation systems. A detailed discussion of the numerous lanthanide-nitrogen species relevant to nitrogen fixation are discussed and are related to the Chatt cycle for nitrogen fixation.
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