期刊
MATERIALS
卷 3, 期 4, 页码 2447-2462出版社
MDPI AG
DOI: 10.3390/ma3042447
关键词
element organic frameworks; EOF; heterogeneous catalysis
We present new element organic frameworks based on Sn, Sb and Bi atoms connected via organic linkers by element-carbon bonds. The open frameworks are characterized by specific surface areas (BET) of up to 445 m(2) g(-1) and a good stability under ambient conditions resulting from a highly hydrophobic inner surface. They show good performance as heterogeneous catalysts in the cyanosylilation of benzaldehyde as a test reaction. Due to their catalytic activity, this class of materials might be able to replace common homogeneous element-organic and often highly toxic catalysts especially in the food industry.
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