Revisiting the iridacycle-catalyzed hydrosilylation of enolizable imines

High Production of Hydrogen on Demand from Silanes Catalyzed by Iridium Complexes as a Versatile Hydrogen Storage System

(2018) David Ventura-Espinosa et al.   ACS Catalysis

Decrypting Transition States by Light: Photoisomerization as a Mechanistic Tool in Brønsted Acid Catalysis

(2017) Polyssena Renzi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridacycles as Catalysts for the Autotandem Conversion of Nitriles into Amines by Hydrosilylation: Experimental Investigation and Scope

(2017) Mustapha Hamdaoui et al.   ORGANOMETALLICS

Hidden Enantioselective Hydrogenation of N-Silyl Enamines and Silyl Enol Ethers in Net C═N and C═O Hydrosilylations Catalyzed by Ru–S Complexes with One Monodentate Chiral Phosphine Ligand

(2017) Susanne Bähr et al.   ORGANOMETALLICS

Exhaustive Chemoselective Reduction of Nitriles by Catalytic Hydrosilylation Involving Cooperative Si–H Bond Activation

(2017) Martin Oestreich et al.   SYNLETT

Two-Silicon Cycle for Carbonyl Hydrosilylation with Nikonov’s Cationic Ruthenium(II) Catalyst

(2017) Julien Fuchs et al.   ACS Catalysis

Selective Hydrosilylation of Esters to Aldehydes Catalysed by Iridium(III) Metallacycles through Trapping of Transient Silyl Cations

(2016) Yann Corre et al.   CHEMISTRY-A EUROPEAN JOURNAL

Evidence of a Donor–Acceptor (Ir–H)→SiR3 Interaction in a Trapped Ir(III) Silane Catalytic Intermediate

(2016) Mustapha Hamdaoui et al.   ORGANOMETALLICS

Hydrosilylation of Ketones, Imines and Nitriles Catalysed by Electrophilic Phosphonium Cations: Functional Group Selectivity and Mechanistic Considerations

(2015) Manuel Pérez et al.   CHEMISTRY-A EUROPEAN JOURNAL

Efficient hydrosilylation of imines using catalysts based on iridium(iii) metallacycles

(2015) Y. Corre et al.   Catalysis Science & Technology

Iridium-Catalyzed Hydrogen Production from Hydrosilanes and Water

(2014) Karin Garcés et al.   ChemCatChem

Outer-Sphere Ionic Hydrosilylation Catalysis

(2014) Manuel Iglesias et al.   ChemCatChem

Direct Catalytic Access to N-Silylated Enamines from Enolizable Imines and Hydrosilanes by Base-Free Dehydrogenative SiN Coupling

(2014) Julia Hermeke et al.   CHEMISTRY-A EUROPEAN JOURNAL

Insight into the Mechanism of Carbonyl Hydrosilylation Catalyzed by Brookhart’s Cationic Iridium(III) Pincer Complex

(2014) Toni T. Metsänen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct observation of a borane–silane complex involved in frustrated Lewis-pair-mediated hydrosilylations

(2014) Adrian Y. Houghton et al.   Nature Chemistry

Hydrolysis and Methanolysis of Silanes Catalyzed by Iridium(III) Bis-N-Heterocyclic Carbene Complexes: Influence of the Wingtip Groups

(2014) Mélanie Aliaga-Lavrijsen et al.   ORGANOMETALLICS

SiH Bond Activation: Bridging Lewis Acid Catalysis with Brookhart’s Iridium(III) Pincer Complex and B(C6F5)3

(2013) Tobias Robert et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Alternative Mechanistic Paradigm for the β-ZHydrosilylation of Terminal Alkynes: The Role of Acetone as a Silane Shuttle

(2013) Manuel Iglesias et al.   CHEMISTRY-A EUROPEAN JOURNAL

Iridium-Catalyzed Hydrosilylative Reduction of Glucose to Hexane(s)

(2013) Matthew P. McLaughlin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Experimental Analysis of the Catalytic Cycle of the Borane-Promoted Imine Reduction with Hydrosilanes: Spectroscopic Detection of Unexpected Intermediates and a Refined Mechanism

(2013) Julia Hermeke et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydroxy-substituted pyridine-like N-heterocycles: versatile ligands in organometallic catalysis

(2013) Wan-Hui Wang et al.   NEW JOURNAL OF CHEMISTRY

Homogeneous catalytic reduction of CO2 with hydrosilanes

(2013) Francisco J. Fernández-Alvarez et al.   Catalysis Science & Technology

Effective Fixation of CO2by Iridium-Catalyzed Hydrosilylation

(2012) Ralte Lalrempuia et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cooperative Catalysis by Iridium Complexes with a Bipyridonate Ligand: Versatile Dehydrogenative Oxidation of Alcohols and Reversible Dehydrogenation-Hydrogenation between 2-Propanol and Acetone

(2012) Ryoko Kawahara et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Room temperature tandem hydroamination and hydrosilation/protodesilation catalysis by a tricarbonylchromium-bound iridacycle

(2012) Wissam Iali et al.   CHEMICAL COMMUNICATIONS

Illuminating the Mechanism of the Borane-Catalyzed Hydrosilylation of Imines with Both an Axially Chiral Borane and Silane

(2012) Marius Mewald et al.   CHEMISTRY-A EUROPEAN JOURNAL

An Efficient Iridium Catalyst for Reduction of Carbon Dioxide to Methane with Trialkylsilanes

(2012) Sehoon Park et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Base-Free Dehydrogenative Coupling of Enolizable Carbonyl Compounds with Silanes

(2012) C. David F. Königs et al.   ORGANIC LETTERS

Facile Catalytic Hydrosilylation of Pyridines

(2011) Dmitry V. Gutsulyak et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Development and Mechanistic Investigation of a Highly Efficient Iridium(V) Silyl Complex for the Reduction of Tertiary Amides to Amines

(2011) Sehoon Park et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dehydrogenative Oxidation of Primary and Secondary Alcohols Catalyzed by a Cp*Ir Complex Having a Functional C,N-Chelate Ligand

(2011) Ken-ichi Fujita et al.   ORGANIC LETTERS

Insertion of nitrene and chalcogenolate groups into the Ir–C σ bond in a cyclometalated iridium(III) complex

(2010) Yiu-Keung Sau et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Cationic Silane σ-Complexes of Ruthenium with Relevance to Catalysis

(2010) Dmitry V. Gutsulyak et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrosilylation with Biscarbene Rh(I) Complexes: Experimental Evidence for a Silylene-Based Mechanism

(2010) Peter Gigler et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrosilylation of Carbonyl-Containing Substrates Catalyzed by an Electrophilic η1-Silane Iridium(III) Complex

(2010) Sehoon Park et al.   ORGANOMETALLICS

Metal Silylenes Generated by Double Silicon-Hydrogen Activation: Key Intermediates in the Rhodium-Catalyzed Hydrosilylation of Ketones

(2009) Nathanaëlle Schneider et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Frustrated Lewis Pairs: Metal-free Hydrogen Activation and More

(2009) Douglas W. Stephan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Structural and Spectroscopic Characterization of an Unprecedented Cationic Transition-Metal η1-Silane Complex

(2008) Jian Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reactions at the Ru-S Bonds of Coordinatively Unsaturated Ruthenium Complexes with Tethered 2,6-Dimesitylphenyl Thiolate

(2008) Yasuhiro Ohki et al.   Chemistry-An Asian Journal

Scope and Mechanism of the Iridium-Catalyzed Cleavage of Alkyl Ethers with Triethylsilane

(2008) Jian Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An Efficient Low-Temperature Route to Polycyclic Isoquinoline Salt Synthesis via C−H Activation with [Cp*MCl2]2(M = Rh, Ir)

(2008) Ling Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

“Frustrated Lewis pairs”: a concept for new reactivity and catalysis

(2008) Douglas W. Stephan   ORGANIC & BIOMOLECULAR CHEMISTRY