期刊
CATALYSIS SCIENCE & TECHNOLOGY
卷 4, 期 11, 页码 3840-3844出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cy01010h
关键词
-
资金
- NSFC [21376135, 51236004]
- 863 program [2012AA051003]
We report, for the first time, an atmospheric pressure synthetic route for nanosized ZSM-5 with 100% yield by decoupling its nucleation and growth process. Under unsealed conditions, abundant crystal nuclei are first formed in the liquid phase and then grow into nanosized ZSM-5 via an improved steam-assisted conversion method using superheated steam as the medium at atmospheric pressure. The obtained nanosized ZSM-5 possesses excellent texture properties, such as high crystallinity, large surface area, tunable Si/Al molar ratio, and uniform size, and exhibits far longer lifetime as well as higher selectivity of total aromatics in the catalytic conversion of methanol to aromatics compared with conventional ZSM-5. This facile route can offer a very promising future for the large-scale preparation of zeolites by a safe and continuous process under atmospheric pressure.
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