期刊
CATALYSIS SCIENCE & TECHNOLOGY
卷 4, 期 10, 页码 3631-3635出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cy00979g
关键词
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资金
- JSPS [25106010]
- MEXT program Elements Strategy Initiative to Form Core Research Center
- Grants-in-Aid for Scientific Research [26289299, 25106010] Funding Source: KAKEN
Supported platinum catalysts have been studied for the acceptor-free dehydrogenative coupling of primary alcohols to esters in the liquid phase under solvent-free conditions in N-2 at 180 degrees C. The activity depends on the support material, and Pt-loaded SnO2 (Pt/SnO2) gives the highest activity. Pt/SnO2 shows higher activity than various transition metals (Ir, Re, Ru, Rh, Pd, Ag, Co, Ni, Cu) loaded on SnO2. The Pt/SnO2 catalyst (1 mol%) selectively converted various primary alcohols to their corresponding esters in moderate to high isolated yield (53-91%). This is the first example of reusable heterogeneous catalysts for the acceptor-free dehydrogenative coupling of primary alcohols to esters under additive-free and solvent-free conditions. Mechanistic and infrared (IR) studies are also shown to discuss the reaction pathway and a possible role of the SnO2 support as Lewis acid sites that activate carbonyl groups of adsorbed aldehyde intermediates.
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