期刊
CATALYSIS SCIENCE & TECHNOLOGY
卷 3, 期 7, 页码 1739-1749出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cy00019b
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资金
- Mitsubishi Chemical Corporation
- JSPS [22-7799]
- doctoral students in Nagoya University
- Grants-in-Aid for Scientific Research [24656490, 25105723] Funding Source: KAKEN
Hydration of various alkenes proceeded over a platinum-loaded titanium oxide photocatalyst. It is notable that, unlike conventional acid-catalysts, the photocatalyst preferentially promoted the hydration according to the anti-Markovnikov rule. The results of some reaction experiments and semiempirical molecular orbital calculations suggested the reaction path of this hydration as follows: an electrophilic surface oxygen radical species formed on the photoexcited titanium oxide attacks a carbon double bond of the alkene to produce an intermediate, followed by the addition of a hydrogen radical formed on the platinum sites to produce an alcohol. The anti-Markovnikov selectivity for each investigated alkene would be determined by the stability of the radical intermediate.
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