4.6 Article

The synthesis and evaluation of highly active Ni2P-MoS2 catalysts using the decomposition of hypophosphites

期刊

CATALYSIS SCIENCE & TECHNOLOGY
卷 2, 期 11, 页码 2356-2360

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cy20146a

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资金

  1. National Natural Science Foundation of China [21073098]
  2. Natural Science Foundation of Tianjin [11JCZDJC21600]
  3. Research Fund for MOE [IRT-0927]
  4. Doctoral Program of Higher Education [20090031110015]
  5. Program for New Century Excellent Talents in University [NCET-10-0481]

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This paper presents the synthesis and evaluation of highly active Ni2P-MoS2 catalysts using the decomposition of hypophosphites. A family of catalysts have been prepared, whose activities were tested using the hydrodesulfurization of 4,6-dimethyldibenzothiophene. Furthermore, the synergy between Ni2P/Al2O3 and MoS2/Al2O3 beds was explained by the remote control model through a migration of hydrogen spillover.

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