期刊
ACS CATALYSIS
卷 3, 期 5, 页码 826-830出版社
AMER CHEMICAL SOC
DOI: 10.1021/cs400043a
关键词
catalysis; hydrosilylation; iron; catalysis; porous organic polymer; catechol
资金
- U.S. Department of Energy [DE-AC02-06CH11357]
- CONACYT (Consejo Nacional de Ciencia y Tecnologia)
- Fundacion Mexico
A single-site, Iron catecholate-containing porous organic polymer was prepared and utilized as a stable and remarkably active catalyst for the hydrosilylation of ketones and aldehydes. In some instances, catalyst loadings of 0.043-2.1 mol % [Fe] Were sufficient for complete hydrosilylation of aldehydes and ketones within IS mm at room temperature. The catalyst can be recycled at least three times without a drop in,catalytic activity. This system is an example of an immobilized homogeneous catalyst with no hemogeneous. analogue.
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