期刊
ACS CATALYSIS
卷 2, 期 6, 页码 1079-1086出版社
AMER CHEMICAL SOC
DOI: 10.1021/cs300092d
关键词
allylic alcohol; redox isomerization; homogeneous catalysis; water-soluble metal complexes; catalysis in water; tandem reaction
资金
- EU: the Spanish MICINN [CTQ2010-20952]
- Junta de Andalucia through PAT [FQM-317]
- Junta de Andalucia [P07-FQM-03092, P09-FQM-5402]
The isomerization of allylic alcohols in water, catalytically mediated by water-soluble metal complexes, is an elegant synthetic procedure for obtaining carbonyl compounds in a completely atom-economical eco-benign process with useful applications in natural-product synthesis and bulk chemical processes. This overview aims to provide a view of the goals attained in catalyzed allylic alcohol isomerization in water and its promising applications.
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