期刊
CHEMICAL SCIENCE
卷 5, 期 6, 页码 2277-2281出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4sc00423j
关键词
-
资金
- NIH [P50-GM086145]
An enantioselective Pd-catalyzed 6-endo-trig reaction for the synthesis of 2-aryl-chromenes has been developed. A systematic optimization of a TADDOL-derived ligand set resulted in the identification of a novel monodentate phosphoramidite-palladium catalyst that accesses 2-aryl-2H-chromenes with high yield and enantioselectivity under mild conditions. The products obtained from this method can be transformed into biologically active compounds through functionalization of the chromene alkene.
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