期刊
CHEMICAL SCIENCE
卷 5, 期 12, 页码 4863-4867出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4sc01152j
关键词
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资金
- W. W. Caruth, Jr Endowed Scholarship
- Robert A. Welch Foundation [I-1748]
- National Institutes of Health [1R01GM102604-01]
- Chilton Foundation Fellowship
- University of Texas System Chemistry and Biology Training Grant
- Sloan Research Fellowship
The 1,4-functionalization of dienes is a synthetically useful strategy for incorporating molecular complexity into a class of simple substrates. We report the aminoarylation of acyclic and cyclic 1,3-dienes via the sequential [4 + 2] cycloaddition with a sulfurdiimide reagent and copper-catalyzed allylic substitution with Grignard reagents. The regioselective and diastereoselective aminoarylation of unsymmetrical dienes is also presented, which highlights the utility of this method for generating products with multiple functional groups and stereocenters.
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