Article
Polymer Science
Roisin A. O'Connell, William N. Sharratt, Nico J. J. Aelmans, Julia S. Higgins, Joao T. Cabral
Summary: The conformation of poly(2,6-diphenyl-p-phenylene oxide) (PPPO) in good and mixed solvents was investigated using small-angle neutron scattering (SANS). The polymer conformation below the overlap concentration is well described by the polymer-excluded volume model, while above it is described by the Ornstein-Zernike expression with a correlation length xi dependent on the concentration and solvent/nonsolvent ratio. Additionally, the characteristic particle radius of polymer nanoparticles scales with polymer concentration and nonsolvent content, while the solution volume per precipitated particle remains nearly constant.
Article
Chemistry, Multidisciplinary
Meng-Kai Lin, Guan-Hao Chen, Ciao-Lin Ho, Wei-Chen Chueh, Joseph Andrew Hlevyack, Chia-Nung Kuo, Tsu-Yi Fu, Juhn-Jong Lin, Chin Shan Lue, Wen-Hao Chang, Noriaki Takagi, Ryuichi Arafune, Tai-Chang Chiang, Chun-Liang Lin
Summary: Monolayer transition metal dichalcogenides show tunability in electronic properties, with bandgap modulation possible through control of tunneling current. Monolayer PtTe2 exhibits a reversible semiconductor-to-metal transition at moderate tunneling current, attributed to its surface electronic structure coupling with the tunneling tip.
Article
Chemistry, Multidisciplinary
Yasuaki Saruta, Katsuaki Sugawara, Hirofumi Oka, Tappei Kawakami, Takemi Kato, Kosuke Nakayama, Seigo Souma, Takashi Takahashi, Tomoteru Fukumura, Takafumi Sato
Summary: The current key challenge in 2D materials is to achieve emergent quantum phenomena in hetero structures by controlling the moire potential created by the periodicity mismatch between adjacent layers. This study demonstrates that the unstable octahedral MoTe2 can be stabilized in a commensurate MoTe2/graphene hetero-bilayer due to the moire potential between the two layers, providing a fresh approach to realize novel 2D quantum phases.
Article
Chemistry, Physical
Adrian Sanchez-Fernandez, Anna E. Leung, Elizabeth G. Kelley, Andrew J. Jackson
Summary: The self-assembly of ionic surfactants in deep eutectic solvents has been demonstrated recently, with the potential for developing new formulated products and templating nanostructured materials. The presence of hydrotropic salts can greatly affect the micellar structure in these solvents, leading to the formation of worm-like aggregates. This study provides insights into salt-induced micellar growth in deep eutectic solvents, showing an increase in micelle elongation and the formation of worm-like micelles with tunable morphology and flexibility through surfactant-salt interactions.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2021)
Article
Chemistry, Multidisciplinary
Fumihiko Tanaka
Summary: The study investigates the thermoreversible gelation of associating polymers in hydrogen-bonding mixed solvents through theoretical modeling, highlighting the optimal gel point where stable, strong gels can be formed. Results show that the preferential adsorption coefficient changes sign and the average molecular weight of the complexes reaches a maximum at this point. Experimental data on poly(vinyl alcohol) in various mixed solvents are compared to the theoretical findings.
Article
Chemistry, Multidisciplinary
Qilong Wu, Xiaoshuai Fu, Ke Yang, Hongyu Wu, Li Liu, Li Zhang, Yuan Tian, Long-Jing Yin, Wei-Qing Huang, Wen Zhang, Ping Kwan Johnny Wong, Lijie Zhang, Andrew T. S. Wee, Zhihui Qin
Summary: This study demonstrates a practical approach to producing highly crystalline monolayer MoSe2 using high-temperature-annealed Au foil as a weakly interacting substrate for atmospheric pressure chemical vapor deposition. The low-temperature scanning tunneling microscopy/spectroscopy measurements reveal a honeycomb structure of MoSe2 with a quasi-particle bandgap of 1.96 eV. The weak coupling between the Au(100) surface and MoSe2 is critical for easy transfer of monolayers to another host substrate.
Article
Chemistry, Multidisciplinary
Qiucheng Li, Xiaolong Liu, Eden B. Aklile, Shaowei Li, Mark C. Hersam
Summary: The study reports the self-assembly of mixed-dimensional lateral heterostructures consisting of 2D metallic borophene and 1D semiconducting armchair-oriented graphene nanoribbons (aGNRs). The systematic study and refinement of on-surface polymerization process from monomers to organometallic intermediates to demetallization result in borophene/aGNR lateral heterojunctions with structurally and electronically abrupt interfaces, providing insight for precise nanoelectronics.
Article
Chemistry, Multidisciplinary
Adrian Sanchez-Fernandez, Andrew J. Jackson, Sylvain F. Prevost, James J. Doutch, Karen J. Edler
Summary: This study demonstrates that in deep eutectic solvents, electrostatic correlations can prevail over long-range electrostatic interactions, and specific counterion condensation can modulate micelle morphology and electrostatic interactions. These findings are rationalized in terms of predominant ion-ion correlations and specific ion effects described by the Hofmeister series.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2021)
Editorial Material
Multidisciplinary Sciences
Sami Malola, Hannu Hakkinen
Summary: This passage discusses how precise knowledge of the chemical composition and atomic structure of nanosized systems can be used for detailed computational work to understand structure-property relations in metal clusters. It also mentions the challenges of developing effective simulation methods to account for cluster-environment interactions, potentially using components of electronic structure theory combined with machine learning algorithms.
NATURE COMMUNICATIONS
(2021)
Article
Chemistry, Multidisciplinary
Daniela Dombrowski, Abdus Samad, Clifford Murray, Marin Petrovic, Pascal Ewen, Thomas Michely, Marko Kralj, Udo Schwingenschlogl, Carsten Busse
Summary: Monolayers of tantalum sulfide were prepared on Au(111) by evaporating Ta in a reactive background of H2S. Different structures were formed under sulfur-rich and sulfur-poor conditions, with TaS identified as a phase derived from 2H-TaS2 by removal of the bottom S layer.
Article
Chemistry, Multidisciplinary
Linghao Yan, Orlando J. Silveira, Benjamin Alldritt, Ondrej Krejci, Adam S. Foster, Peter Liljeroth
Summary: The successful fabrication of a 2D monolayer Cu-dicyanoanthracene MOF on an epitaxial graphene surface with long-range order and the study of its structural and electronic properties using low-temperature scanning tunneling microscopy and spectroscopy, along with density-functional theory calculations, show promise for future applications in electronic devices. The ability to access multiple molecular charge states in the 2D MOF using tip-induced local electric fields suggests potential for fabricating and characterizing 2D MOFs with engineered electronic states.
ADVANCED FUNCTIONAL MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Tianchao Niu, Miao Zhou
Summary: Boron, the lightest metalloid element, has similar characteristics to carbon in planar and cage molecules. Recent studies have focused on the various structures of mono- and bi-layer boron and their potential applications in materials science. This review highlights the latest achievements in the epitaxial growth of bilayer borophene on noble metal surfaces, discussing the roles of substrate and growth conditions. Bilayer borophene exhibits superior properties compared to single-layer borophene, but its synthesis remains challenging and requires further research.
Article
Chemistry, Multidisciplinary
Viliam Vano, Somesh Chandra Ganguli, Mohammad Amini, Linghao Yan, Maryam Khosravian, Guangze Chen, Shawulienu Kezilebieke, Jose L. Lado, Peter Liljeroth
Summary: Unconventional superconductors, particularly nodal superconductors, have been a focus in modern quantum materials research. This study demonstrates the existence of nodal superconductivity in pristine monolayer 1H-TaS2 using low-temperature scanning tunneling microscopy (STM) and spectroscopy (STS) experiments. It is also found that non-magnetic disorder can drive the nodal state to a conventional gapped s-wave state, and many-body excitations emerge near the gap edge, indicating a potential unconventional pairing mechanism.
ADVANCED MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Ricardo Javier Pena Roman, Remi Bretel, Delphine Pommier, Luis Enrique Parra Lopez, Etienne Lorchat, Elizabeth Boer-Duchemin, Gerald Dujardin, Andrei G. Borisov, Luiz Fernando Zagonel, Guillaume Schull, Stephane Berciaud, Eric Le Moal
Summary: This study demonstrates the local and electrical control of photoluminescence in monolayer WS2 using a nonplasmonic tip and tunneling current of a scanning tunneling microscope. The results show that short-range photoluminescence quenching is present due to near-field electromagnetic effects, independent of the bias voltage. Additionally, a bias-voltage-dependent long-range photoluminescence quenching is observed when the sample is positively biased.
Article
Chemistry, Multidisciplinary
Youness Kaddar, Wei Zhang, Hanna Enriquez, Yannick J. Dappe, Azzedine Bendounan, Gerald Dujardin, Omar Mounkachi, Abdallah El Kenz, Abdelilah Benyoussef, Abdelkader Kara, Hamid Oughaddou
Summary: Blue phosphorene, an allotrope of black phosphorene, exhibits Dirac fermions similar to graphene when grown on a Cu(111) surface. This suggests that high-speed electronic devices based on ballistic transport at room temperature could be achieved using blue phosphorene.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Xindi Liu, Huayan Yang, Yuxiang Chen, Ye Yang, Lionel Porcar, Aurel Radulescu, Stefan Guldin, Rongchao Jin, Francesco Stellacci, Zhi Luo
Summary: In this study, small-angle neutron scattering (SANS) was used to quantify the structure parameters of silver and gold nanoclusters in solution, providing insights into the counterions layer and molecular weight. This alternative characterization tool offers a way to study nanoclusters without the need for crystallization or gas phase ionization.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Environmental Sciences
Fangyuan Zheng, Pedro M. Martins, Joana M. Queiros, Carlos J. Tavares, Jose Luis Vilas-Vilela, Senentxu Lanceros-Mendez, Javier Reguera
Summary: Antibiotics are a harmful contaminant in water and contribute to the generation of antibiotic-multiresistant organisms. Plasmonic-photocatalysis using solar energy presents a promising solution for their removal. In this study, hybrid TiO2:Au nanostars were synthesized and two porous membranes were prepared as substrates for their immobilization.
Article
Chemistry, Multidisciplinary
Lucio Litti, Javier Reguera, Leixuri B. Berganza, Moreno Meneghetti, Senentxu Lanceros-Mendez
Summary: Surface-enhanced Raman scattering (SERS) is a promising method for detecting contaminants or biomolecules in water. Gold-coated magnetite nanorods as a multifunctional SERS substrate can achieve quick magnetic separation and excellent Raman enhancement in both dispersion and magnetic concentration.
Article
Engineering, Electrical & Electronic
Edoardo Ragusa, Rodolfo Zunino, Valentina Mastronardi, Mauro Moglianetti, Pier P. Pompa, Paolo Gastaldo
Summary: This research presents a low-cost, lightweight, and automatic readout system for accurately quantifying the level of cisplatin in a colorimetric POC device. The system uses an RGB camera to capture color changes in a test tube, and a machine learning-based inference function to estimate the concentration of cisplatin. The training strategy incorporates ensemble learning to handle small training sets and supports a gray-box model for interpretability. Experimental results demonstrate that the proposed readout system outperforms the state-of-the-art system for quantifying cisplatin levels in a colorimetric POC device.
IEEE SENSORS LETTERS
(2022)
Article
Chemistry, Multidisciplinary
Diana Nelli, Valentina Mastronardi, Rosaria Brescia, Pier Paolo Pompa, Mauro Moglianetti, Riccardo Ferrando
Summary: The growth of pyramidal platinum nanocrystals is caused by the adsorption of hydrogen on {100} facets, which results in a peculiar type of symmetry breaking. The size-dependent adsorption energies of hydrogen atoms on {100} facets hinder the growth of pyramidal shapes only when they are sufficiently large. The absence of pyramidal nanocrystals in experiments without hydrogen confirms the crucial role of hydrogen adsorption.
Article
Chemistry, Multidisciplinary
Ester Canepa, Davide Bochicchio, Giorgia Brosio, Paulo Henrique Jacob Silva, Francesco Stellacci, Silvia Dante, Giulia Rossi, Annalisa Relini
Summary: Membrane fusion is essential for eukaryotic cell functionality and is regulated by specialized proteins, lipid composition, and ion environment. Liposomes decorated with amphiphilic Au nanoparticles (AuLips) have been shown to act as tunable fusion machinery, triggered by divalent ions and tunable by liposome cholesterol content. This research provides new mechanistic details on the fusogenic activity of AuNPs and demonstrates their potential as artificial fusogenic agents for biomedical applications.
Article
Chemistry, Multidisciplinary
Weina Liu, Yong Zhu, Francesco Stellacci
Summary: Researchers demonstrated a recyclable PCR kit to reduce dependence on nucleic acid resources and address the shortage of PCR kits during the pandemic.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2023)
Article
Chemistry, Multidisciplinary
Irena Levin, Aurel Radulescu, Lucy Liberman, Yachin Cohen
Summary: This research aims to characterize the adsorption morphology of block copolymer dispersants of the styrene-block-4-vinylpyridine family (S4VP) on the surface of multi-walled carbon nanotubes (MWCNT) in a polar organic solvent, N,N-dimethyl formamide (DMF). The results show that the block copolymers adsorb onto the MWCNT surface as a continuous coverage of low polymer concentration. Increasing the PS molecular weight increases the thickness of the adsorbed layer but decreases the overall polymer concentration within it. These results are relevant for the ability of dispersed CNTs to form a strong interface with matrix polymers in composites, due to the extension of the 4VP chains allowing for entanglement with matrix chains.
Article
Chemistry, Multidisciplinary
Suiyang Liao, Lixia Wei, Arthur Eliot Bouchez, Francesco Stellacci
Summary: Most studied parameters of nanoparticles' interactions with cells are currently static, while proteins have dynamic structures. This study focuses on single-chain polymeric nanoparticles (SCPNs) that undergo dynamic changes. By creating multiple sets of particles with identical polymer chains, it was found that cell uptake discriminates between dynamic and static SCPN isomers. Dynamic isomers are uptaken more through different endocytic pathways, while static isomers access the cytosol more efficiently.
Article
Pharmacology & Pharmacy
Yong Zhu, Andrey A. A. Sysoev, Paulo H. Jacob Silva, Marine Batista, Francesco Stellacci
Summary: We have reported that CD-6'SLN irreversibly deactivates virions and improves mice survival in H1N1 infection model. CD-6'SLN interacts with the viral envelope protein HA, but not with NA, inhibiting influenza virus through an extracellular mechanism. Our findings suggest that combining viral protein-specific epitopes with hydrophobic linkers provides a strategy for developing antiviral drugs.
Article
Chemistry, Physical
Fangyuan Zheng, Joana M. Queiros, Pedro M. Martins, Roberto Fernandez de Luis, Arkaitz Fidalgo-Marijuan, Jose L. Vilas-Vilela, Senentxu Lanceros-Mendez, Javier Reguera
Summary: A large number of emerging contaminants, such as pharmaceuticals, are difficult to remove from water bodies using conventional treatment methods, leading to serious environmental issues. Semiconductor-based photocatalysis has emerged as an exciting solution for the degradation of these pollutants. However, the diverse chemical composition of pharmaceutical pollutants poses challenges in selecting suitable photocatalysts for efficient and broad removal, necessitating systematic studies on the physicochemical properties of photocatalysts and pollutants.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2023)
Article
Electrochemistry
Marilena Isabella Zappia, Valentina Mastronardi, Sebastiano Bellani, Yong Zuo, Gabriele Bianca, Luca Gabatel, Matteo Gentile, Ahmad Bagheri, Hossein Beydaghi, Filippo Drago, Michele Ferri, Mauro Moglianetti, Pier Paolo Pompa, Liberato Manna, Francesco Bonaccorso
Summary: Efficient and cost-effective water splitting electrolyzers are crucial for achieving climate neutrality. This study explores Pt-based nanostructured cathodes with graphene as a nanocatalyst support. The Pt/graphene catalysts outperform traditional Pt/C catalysts in terms of hydrogen evolution reaction (HER) activity and performance durability. This study demonstrates the potential of graphene as a conductive support for nanostructured cathodes and highlights the improved performance of alkaline electrolyzers.
ELECTROCHIMICA ACTA
(2023)
Article
Chemistry, Multidisciplinary
Fumitoshi Kaneko, Aurel Radulescu, Hiroshi Nakagawa
Summary: Small-angle neutron scattering (SANS) is a powerful technique for studying the higher-order structure of soft matter. Combining different types of structural information obtained by other methods can increase the reliability of SANS profile analysis for complex multi-component systems. To overcome the issue of samples suitable for SANS being too thick for typical transmission FTIR method, a new simultaneous measurement system that uses attenuated total reflectance (ART) sampling method for FTIR spectroscopy has been developed.
JOURNAL OF APPLIED CRYSTALLOGRAPHY
(2023)
Article
Nanoscience & Nanotechnology
Esraa Samy Abu Serea, Inaki Orue, Jose Angel Garcia, Senentxu Lanceros-Mendez, Javier Reguera
Summary: Nanohyperthermia therapies are a promising alternative for treating cancer tumors, and multifunctional nanosystems offer advances in this field. Optimizing the size and shape of nanomaterials improves the efficiency of hyperthermia therapies.
ACS APPLIED NANO MATERIALS
(2023)
Proceedings Paper
Computer Science, Artificial Intelligence
Edoardo Ragusa, Valentina Mastronardi, Deborah Pedone, Mauro Moglianetti, Pier Paolo Pompa, Rodolfo Zunino, Paolo Gastaldo
Summary: The introduction of POC devices is revolutionizing diagnostics, but their accuracy falls short compared to traditional laboratory-based methods. Automated readout using machine learning can significantly enhance the quality of POC analysis while maintaining portability and real-time results. This paper proposes the use of random-based neural networks to accurately assess salivary antioxidant levels and demonstrates their superiority through experiments.
ADVANCES IN SYSTEM-INTEGRATED INTELLIGENCE, SYSINT 2022
(2023)
Article
Chemistry, Multidisciplinary
Alexander M. Prophet, Kritanjan Polley, Gary J. Van Berkel, David T. Limmer, Kevin R. Wilson
Summary: The oxidation kinetics of iodide by ozone at the air-water interface is studied in single microdroplets. Molecular simulations and kinetic modeling are used to understand the underlying multiphase mechanism.
Article
Chemistry, Multidisciplinary
Rong Zhang, Jiajing Lan, Fei Wang, Shumei Chen, Jian Zhang
Summary: By utilizing 1,1'-ferrocene dicarboxylic acid as a chelating and surface protection ligand, we have synthesized multi-nuclear indium oxide clusters with varying nuclear sizes, including heptanuclear and thirteen-nuclear clusters. These clusters possess labile coordination sites, allowing for structural modification and self-assembly, resulting in the formation of various cluster structures.
Article
Chemistry, Multidisciplinary
Hui Wang, Hui Liu, Mingsen Wang, Jiaheng Hou, Yongjun Li, Yuancheng Wang, Yingjie Zhao
Summary: Two supramolecular complexes were prepared using CBs and M1, and their single-crystal structures were analyzed by SCXRD. The unexpected 1:2 self-assembly structure between M1 and CB[8] was discovered for the first time. These complexes exhibit unique photophysical properties and provide valuable information about the structure and photophysical properties of supramolecular complexes.
Article
Chemistry, Multidisciplinary
Chang-Hee Lee, Sookil Park, Sanggil Kim, Ji Young Hyun, Hyun Soo Lee, Injae Shin
Summary: The epidermal growth factor receptor (EGFR) is a cell-surface glycoprotein involved in cell proliferation and tumor development. This study used a fluorescently labeled EGFR to investigate its time-dependent endocytosis in live cells and found that appended glycans affect EGFR internalization. Additionally, the study detected sialic acid residues attached to EGFR on the live cell surface using FRET-based imaging. This research provides valuable insights into the cellular functions of EGFR.
Article
Chemistry, Multidisciplinary
Subhankar Sahu, Lokesh Kumar, Sumita Das, Dipti Gupta, Ruchi Anand
Summary: This study proposes a strategy that combines organic electronics with biosensor scaffolds to create a compact device for monitoring environmental aromatic pollution. By coupling biosensing protein MopR with an organic electrochemical transistor (OECT), a sensor module capable of efficient detection of phenol was designed. Exclusive phenol detection with minimal loss of sensitivity could be achieved in complex pollutant mixtures and real environmental samples.
Review
Chemistry, Multidisciplinary
Changseok Lee, Hyung-Joon Kang, Sungwoo Hong
Summary: The formation of C-N bonds through hydroamination reactions catalyzed by nickel hydrides has been a topic of recent interest. This approach offers a way to efficiently transform a variety of alkene and alkyne substrates into compounds enriched with C-N bonds. The review provides a concise overview of the underlying reaction mechanisms and aims to stimulate further progress in NiH-catalytic techniques and catalyst design.
Article
Chemistry, Multidisciplinary
Yueci Wu, Lu-Lu Sun, Hai-Hao Han, Xiao-Peng He, Weiguo Cao, Tony D. James
Summary: Drug-induced liver injury (DILI) is a common cause of acute liver failure in the USA and Europe, but most cases can be recovered or prevented by discontinuing the offending drug. Recent research has found that peroxynitrite (ONOO-) can be used as a potential indicator for early diagnosis of DILI, and there is an urgent need to establish a method to detect and track peroxynitrite in DILI cases. In this study, a FRET-based nano fluorescent probe CD-N-I was developed, which showed high selectivity and sensitivity in detecting peroxynitrite. The probe successfully detected exogenous peroxynitrite in live cells and endogenous peroxynitrite in APAP-induced liver injury of HepG2 cells.
Article
Chemistry, Multidisciplinary
Dmitry L. Lipilin, Mikhail O. Zubkov, Mikhail D. Kosobokov, Alexander D. Dilman
Summary: This article describes a direct photocatalytic method for the thiolation of unprotected acids, which was previously challenging. By using a thionocarbonate reagent with an N-O bond, the efficient conversion of carboxylic acids to thiols is achieved.
Article
Chemistry, Multidisciplinary
Jason Malenfant, Lucille Kuster, Yohann Gagne, Kouassi Signo, Maxime Denis, Sylvain Canesi, Mathieu Frenette
Summary: Raman microscopy can reveal compound-specific vibrational fingerprints without sample preparation. The combination of efficient theoretical calculations and a user-friendly software can accurately predict peak positions and provide match scores to assist with structure determination.
Article
Chemistry, Multidisciplinary
Jayoh A. Hernandez, Paul S. Micus, Sean Alec Lois Sunga, Luca Mazzei, Stefano Ciurli, Gabriele Meloni
Summary: Essential trace metals play crucial roles in the survival and virulence of bacterial pathogens. Helicobacter pylori requires nickel for colonization and persistence in the stomach, and NixA is an essential nickel transporter in this process. This study characterizes the selectivity and electrogenic nature of NixA-mediated nickel transport.
Article
Chemistry, Multidisciplinary
Tarali Devi, Kuheli Dutta, Jennifer Deutscher, Stefan Mebs, Uwe Kuhlmann, Michael Haumann, Beatrice Cula, Holger Dau, Peter Hildebrandt, Kallol Ray
Summary: This study emphasizes the importance of subtle electronic changes and secondary interactions in the stability of biologically relevant metal-dioxygen intermediates. It also shows that the role of the chloride ligand in stabilizing the Fe-III-(OOBu)-Bu-t moiety can extend to other anions, including the thiolate ligand.
Article
Chemistry, Multidisciplinary
Jacqueline R. Santhouse, Jeremy M. G. Leung, Lillian T. Chong, W. Seth Horne
Summary: By studying the folding kinetics and mechanism of the BdpA sequence, researchers found that altering the backbone connectivity can affect protein folding. This suggests that protein mimetic chains have a significant degree of plasticity in transitioning between unfolded and folded states.
Article
Chemistry, Multidisciplinary
Divanshu Gupta, Ralf Einholz, Holger F. Bettinger
Summary: This study presents the first direct spectroscopic evidence of a cyclic seven-membered iminoborane. Compared to linear amino-iminoboranes, this cyclic iminoborane exhibits weakened bond strength and lower Lewis acidity value. The study suggests that the reduced ring strain of cyclic iminoborane prevents nitrogen fixation but allows facile (2 + 2) cycloaddition reaction with C2H4.
Article
Chemistry, Multidisciplinary
Renny Mathew, Aniruddha Mazumder, Praveen Kumar, Julie Matula, Sharmarke Mohamed, Petr Brazda, Mahesh Hariharan, Brijith Thomas
Summary: This study reveals the packing arrangement of partially disordered nitro-perylenediimide (NO2-PDI) using a synergistic approach that combines 3D ED, ssNMR, and DFT techniques. By overcoming these challenges, this methodology opens up new avenues for material characterization, driving exciting advancements in the field.
