期刊
CHEMICAL SCIENCE
卷 3, 期 2, 页码 476-484出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1sc00689d
关键词
-
资金
- Natural Science Foundation of China [20825724, 21107071]
- Shanghai Government [S30406, 10dj1400100, 10PJ1408200, 11YZ88, ssd10014]
- Shanghai Key Laboratory of Rare Earth Functional Materials
- National Science Foundation [CHE-1057569]
A novel class of heterogenized organometallic catalysts was synthesized by chelating various metallic ions with neutral coordinate phosphine oxide ligands incorporated into the network of a phenolformaldehyde resin with ordered mesoporous structure and used in a variety of water-medium organic reactions. The as-prepared M-NCP-MPs catalysts (M = Pd2+, Au+, Rh+ and Ni2+) exhibited comparable activity and selectivity with their corresponding homogeneous catalysts owing to the large surface area, ordered mesopore channels, uniform distribution of active sites, and strong surface hydrophobicity, which facilitated the adsorption of organic reactants, especially in aqueous solution. More importantly, these catalysts showed excellent durability and could be used repetitively even in alkaline media owing to the strong stability against alkaline corrosion.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据