NHC-catalysed, chemoselective crossed-acyloin reactions

Extending NHC-Catalysis: Coupling Aldehydes with Unconventional Reaction Partners

(2011) Akkattu T. Biju et al.   ACCOUNTS OF CHEMICAL RESEARCH

Highly Asymmetric NHC-Catalyzed Hydroacylation of Unactivated Alkenes

(2011) Isabel Piel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Exerting control over the acyloin reaction

(2011) Timothy J. Donohoe et al.   CHEMICAL COMMUNICATIONS

Employing homoenolates generated by NHC catalysis in carbon–carbon bond-forming reactions: state of the art

(2011) Vijay Nair et al.   CHEMICAL SOCIETY REVIEWS

A Family of Thiazolium Salt Derived N-Heterocyclic Carbenes (NHCs) for Organocatalysis: Synthesis, Investigation and Application in Cross-Benzoin Condensation

(2011) Isabel Piel et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Dual Secondary Amine/N-Heterocyclic Carbene Catalysis in the Asymmetric Michael/Cross-Benzoin Cascade Reaction of β-Oxo Sulfones with Enals

(2011) Dieter Enders et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Switching Regioselectivity in Crossed Acyloin Condensations between Aromatic Aldehydes and Acetaldehyde by AlteringN-Heterocyclic Carbene Catalysts

(2011) Ming Yu Jin et al.   ORGANIC LETTERS

N-Heterocyclic carbene-catalyzed hydroacylation of isatins with aldehydes: access to 3-acyloxy-1,3-dihydro-2H-indol-2-ones

(2011) Ding Du et al.   TETRAHEDRON

α-Diketones as acyl anion equivalents: a non-enzymatic thiamine-promoted route to aldehyde–ketone coupling in PEG400 as recyclable medium

(2011) Olga Bortolini et al.   TETRAHEDRON

Enamine/carbene cascade catalysis in the diastereo- and enantioselective synthesis of functionalized cyclopentanones

(2011) Kerem E. Ozboya et al.   Chemical Science

The effect of the N-mesityl group in NHC-catalyzed reactions

(2011) Jessada Mahatthananchai et al.   Chemical Science

Intermolecular N-Heterocyclic Carbene Catalyzed Hydroacylation of Arynes

(2010) Akkattu T. Biju et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N-heterocyclic carbene catalysed asymmetric cross-benzoin reactions of heteroaromatic aldehydes with trifluoromethyl ketones

(2010) Dieter Enders et al.   CHEMICAL COMMUNICATIONS

Direct and efficient N-heterocyclic carbene-catalyzed hydroxymethylation of aldehydes

(2010) Nadine Kuhl et al.   CHEMICAL COMMUNICATIONS

Enantioselective benzoin condensation catalyzed by bifunctional N-heterocyclic carbenes

(2010) XueLiang Huang et al.   CHINESE SCIENCE BULLETIN

Bacillus stearothermophilus acetylacetoin synthase: A new catalyst for C–C bond formation

(2010) Pier Paolo Giovannini et al.   JOURNAL OF MOLECULAR CATALYSIS B-ENZYMATIC

Delineating Origins of Stereocontrol in Asymmetric Pd-Catalyzed α-Hydroxylation of 1,3-Ketoesters

(2010) Alexander M. R. Smith et al.   JOURNAL OF ORGANIC CHEMISTRY

Highly Chemoselective Direct Crossed Aliphatic−Aromatic Acyloin Condensations with Triazolium-Derived Carbene Catalysts

(2010) Sarah E. O’Toole et al.   JOURNAL OF ORGANIC CHEMISTRY

N-Heterocyclic Carbene-Catalyzed Cascade Reaction Involving the Hydroacylation of Unactivated Alkynes

(2010) Akkattu T. Biju et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N-silyl oxyketene imines are underused yet highly versatile reagents for catalytic asymmetric synthesis

(2010) Scott E. Denmark et al.   Nature Chemistry

N-Heterocyclic carbene-catalyzed (NHC) three-component domino reactions: highly stereoselective synthesis of functionalized acyclic ε-ketoesters

(2010) Jianze Ma et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

NHC-Catalyzed Spiro Bis-Indane Formation via Domino Stetter−Aldol−Michael and Stetter−Aldol−Aldol Reactions

(2010) Eduardo Sánchez-Larios et al.   ORGANIC LETTERS

1,3-Bis(2,4,6-trimethylphenyl)imidazolium chloride in combination with triethylamine: an improved catalytic system for hydroacylation/reduction of activated ketones

(2010) M. Sreenivasulu et al.   TETRAHEDRON LETTERS

A Direct Intermolecular Cross-Benzoin Type Reaction: N-Heterocyclic Carbene-Catalyzed Coupling of Aromatic Aldehydes with Trifluoromethyl Ketones

(2009) Dieter Enders et al.   ADVANCED SYNTHESIS & CATALYSIS

N-Heterocyclic Carbene-Catalyzed Monoacylation of 1,4-Naphthoquinones with Aldehydes

(2009) María Teresa Molina et al.   JOURNAL OF ORGANIC CHEMISTRY

Catalytic Intermolecular Aldehyde−Ketone Coupling via Acyl Phosphonates

(2009) Ayhan S. Demir et al.   JOURNAL OF ORGANIC CHEMISTRY

Highly Enantioselective Benzoin Condensation Reactions Involving a Bifunctional Protic Pentafluorophenyl-Substituted Triazolium Precatalyst

(2009) Louise Baragwanath et al.   JOURNAL OF ORGANIC CHEMISTRY

Diastereoselective Synthesis of 4-Hydroxytetralones via a Cascade Stetter−Aldol Reaction Catalyzed byN-Heterocyclic Carbenes

(2009) Fang-Gang Sun et al.   JOURNAL OF ORGANIC CHEMISTRY

Asymmetric Synthesis of Functionalized Cyclopentanones via a Multicatalytic Secondary Amine/N-Heterocyclic Carbene Catalyzed Cascade Sequence

(2009) Stephen P. Lathrop et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N-Heterocyclic Carbene-Catalyzed Hydroacylation of Unactivated Double Bonds

(2009) Keiichi Hirano et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The enantioselective benzoin condensation promoted by chiral triazolium precatalysts: stereochemical control via hydrogen bonding

(2009) Sarah E. O'Toole et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Lanthanum Tricyanide-Catalyzed Acyl Silane−Ketone Benzoin Additions

(2009) James C. Tarr et al.   ORGANIC LETTERS

Stereoselective Synthesis of Bicyclic Tertiary Alcohols with Quaternary Stereocenters via Intramolecular Crossed Benzoin Reactions Catalyzed byN-Heterocyclic Carbenes

(2009) Tadashi Ema et al.   ORGANIC LETTERS

Impact of Solvent Polarity on N-Heterocyclic Carbene-Catalyzed β-Protonations of Homoenolate Equivalents

(2009) Brooks E. Maki et al.   ORGANIC LETTERS

Stereoselective Synthesis of γ-ButyrolactonesviaOrganocatalytic Annulations of Enals and Keto Esters

(2008) Yi Li et al.   ADVANCED SYNTHESIS & CATALYSIS

Tandem multi-step synthesis of C-carboxyazlactones promoted by N-heterocyclic carbenes

(2008) Craig D. Campbell et al.   CHEMICAL COMMUNICATIONS

d-Camphor-derived triazolium salts for catalytic intramolecular crossed aldehyde–ketone benzoin reactions

(2008) Yi Li et al.   CHEMICAL COMMUNICATIONS

Development of Chiral Bicyclic Triazolium Salt Organic Catalysts: The Importance of theN-Aryl Substituent

(2007) Tomislav Rovis   CHEMISTRY LETTERS