期刊
CHEMICAL SCIENCE
卷 2, 期 2, 页码 229-232出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0sc00500b
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资金
- Australian Research Council (ARC)
Practical syntheses of the first six members of the ivyane (1,1-oligocyclopropane) family of fundamental hydrocarbons have been achieved from the cross-conjugated polyenes known as dendralenes. Evidence for helical conformations in both the solid state and in solution is presented. [6]Ivyane exhibits one of the highest experimental heats of combustion recorded for a hydrocarbon. Ring-opening reactions of ivyanes furnish new and interesting structures that are difficult to access by conventional means.
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