期刊
JOURNAL OF MATERIALS CHEMISTRY A
卷 3, 期 13, 页码 6929-6934出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ta00115c
关键词
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资金
- Air Force Office of Scientific Research [FA9550-09-1-0426]
- Asian Office of Aerospace RD [FA2386-11-1-4072]
- Office of Naval Research [N00014-14-1-0170]
- Boeing Foundation
- US NSF [CHE-1265945]
Two n-type molecular organic semiconductors (TI-BDF1 and TI-BDF2) consisting of thiophene-substituted indolin-2-one (TI) and benzodifurandione (BDF) with different branched side-chains have been synthesized to study the effect of molecular structure on molecular order, liquid crystal (LC) properties, and charge-transport. By tuning the branching point of the side-chains, TI-BDF2 shows a preferable edge-on p-face orientation and a high degree of liquid crystallinity, resulting in 4 orders of magnitude higher electron mobility than that of TI-BDF1. Subsequent n-doping of TI-BDF2 thin film with a thermally stable phosphonium salt affords a high electrical conductivity of 0.4 S cm(-1).
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