Article
Materials Science, Ceramics
Inna A. Zvonareva, Anna V. Kasyanova, Artem P. Tarutin, Gennady K. Vdovin, Julia G. Lyagaeva, Dmitry A. Medvedev
Summary: Systematic studies on BaZr0.8-xSnxSc0.2O3-delta revealed that the composition with x = 0.1 exhibits the highest values in terms of ionic and grain conductivities. Low-level substitution of Zr4+ with Sn4+ ions shows promise in designing new proton-conducting electrolytes for high-temperature applications.
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
(2022)
Article
Materials Science, Multidisciplinary
Liling Zhang, Yanru Yin, Yangsen Xu, Shoufu Yu, Lei Bi
Summary: Sc-doped Sr2Fe1.5MO0.5O6-delta shows improved proton diffusion rate, reduced vacancy formation energy and increased catalytic activity. The H-SOFC based on SFMSc cathode exhibits excellent performance and stability.
SCIENCE CHINA-MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Kang Zhu, Yi Yang, Daoming Huan, Xueyu Hu, Nai Shi, Yun Xie, Xinyu Li, Changrong Xia, Ranran Peng, Yalin Lu
Summary: This study demonstrates that K+ doping can improve the proton conduction performance of SCN cathode, which is of great significance for P-SOFCs.
Article
Materials Science, Multidisciplinary
Yueh-Lin Lee, Yuhua Duan, Dan C. Sorescu, Wissam A. Saidi, Dane Morgan, Kalapos Thomas, William K. Epting, Gregory Hackett, Harry Abernathy
Summary: Density functional theory was used to study the effect of humidity and gas pressure on the defect chemistry and transport properties of proton conducting oxide. It was found that introducing oxygen vacancies can increase the concentration of proton species, but decrease the overall proton diffusivity.
Article
Chemistry, Physical
Donglin Han, Peng Zhong, Xiaorong Zhang, Lulu Jiang
Summary: In this study, the changes in the local structure of proton-conducting pyrochlore oxides upon hydration were investigated using EXAFS analysis. It was found that doping proper sites can significantly increase proton conductivity in oxides.
JOURNAL OF MATERIALS CHEMISTRY A
(2022)
Article
Chemistry, Physical
Amir Masoud Dayaghi, Jonathan M. Polfus, Ragnar Strandbakke, Anuj Pokle, Laura Almar, Sonia Escolastico, Einar Vollestad, Jose M. Serra, Reidar Haugsrud, Truls Norby
Summary: The effects of NiO, ZnO, and CuO sintering additives on proton conducting electrolytes were studied. The additives decreased the effective acceptor concentration, with NiO having the largest impact. NiO and CuO were found to optimize both sintering and hydration.
SOLID STATE IONICS
(2023)
Article
Materials Science, Ceramics
Nur Wardah Norman, Mahendra Rao Somalu, Andanastuti Muchtar, Nurul Akidah Baharuddin, S. A. Muhammed Ali, Abul Kalam Azad, Jarot Raharjo, Deni Shidqi Khaerudini, Nigel P. Brandon
Summary: Proton-conducting Sr0.6Ba0.4Ce0.9M0.1O3-8 (M = In, Pr, Ga) electrolytes without Zr were synthesized using the glycine-nitrate process for intermediate-temperature solid oxide fuel cell (SOFC) applications. The electrolyte powders were analyzed for thermal decomposition and crystalline structure. The morphological structure, chemical stability, and proton conductivity of the electrolyte pellets were examined. It was determined that Sr0.6Ba0.4Ce0.9In0.1O3-8 is the best electrolyte in terms of sinterability, chemical stability, and proton conductivity.
CERAMICS INTERNATIONAL
(2023)
Article
Chemistry, Inorganic & Nuclear
Anna Niemczyk, Anna Stepien, Kacper Cichy, Juliusz Dabrowa, Zijia Zhang, Bartlomiej Gedziorowski, Kun Zheng, Hailei Zhao, Konrad Swierczek
Summary: Ruddlesden-Popper-type oxides Nd2-xNi0.75Cu0.2M0.05O4 +/-delta (where x = 0 and 0.1; M = Sc, Ga, and In) were synthesized via a sol-gel method and characterized. Materials with Nd-site deficiency show potential applications as oxygen transport membranes with relatively high oxygen fluxes.
JOURNAL OF SOLID STATE CHEMISTRY
(2021)
Article
Chemistry, Physical
Mei Gui Vanessa Wee, Amutha Chinnappan, Runxin Shang, Poh Seng Lee, Seeram Ramakrishna
Summary: Cooling processes, from residences to industries, require a lot of energy and are essential. This study introduces MIL-101(Cr), a new desiccant, to heat exchangers for more efficient cooling. By improving the synthesis method and using a special binder, the MIL-101(Cr)-coated heat exchanger shows improved water uptake capacity and lower regeneration temperature.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Ao Zhen, Guanyu Zhang, Ao Wang, Feng Luo, Jiehua Li, Hong Tan, Zhen Li
Summary: In this study, a solvent-free microemulsion method was used to synthesize waterborne polyurethane (WPU) material with high retention of mechanical properties and satisfactory water absorption rates. The material showed excellent biocompatibility and has broad application potential in the field of biomedicine.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Review
Chemistry, Physical
Wensong Ge, Rui Wang, Xiaoyang Zhu, Houchao Zhang, Luanfa Sun, Fei Wang, Hongke Li, Zhenghao Li, Xinyi Du, Huangyu Chen, Fan Zhang, Huifa Shi, Huiqiang Hu, Yongming Xi, Jiankang He, Liang Hu, Hongbo Lan
Summary: This paper reviews the research on the surface tension of eutectic gallium-indium alloys (EGaIn) in the field of stretchable electronics. It covers the principles of oxide layer formation, factors influencing surface tension, and methods for surface modification of liquid metals. The paper also discusses the applications of EGaIn surface modification in different fields and highlights the challenges still faced and the future outlook.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Review
Chemistry, Physical
Xiang Song, Lianghao Jia, Zhengen Wei, Tao Xiang, Shaobing Zhou
Summary: This paper provides an overview of the application, preparation, and role of biomimetic structures in solar evaporators with improved evaporation rate and lifetime.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Wei Yuan, Qian Deng, Dong Pan, Xiang An, Canyang Zhao, Wenjun Su, Zhengmin He, Qiang Sun, Ran Ang
Summary: Optimizing the performance of n-type PbTe thermoelectric materials is crucial for practical applications. Dynamic doping has emerged as an effective method to improve the performance of n-type PbTe by optimizing the carrier concentration. This study demonstrates the significance of Mn alloying in enhancing the performance of Ag-doped n-type PbTe by creating a hierarchical structure to suppress thermal transport and improving the Seebeck coefficient.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Review
Chemistry, Physical
Xiaoyan Wang, Meiqi Geng, Shengjun Sun, Qian Xiang, Shiyuan Dong, Kai Dong, Yongchao Yao, Yan Wang, Yingchun Yang, Yongsong Luo, Dongdong Zheng, Qian Liu, Jianming Hu, Qian Wu, Xuping Sun, Bo Tang
Summary: This review provides a comprehensive analysis of the progress and challenges in the field of bifunctional electrocatalysts and efficient electrolyzers for seawater splitting. It summarizes recent advancements and proposes future perspectives for highly efficient bifunctional electrocatalysts and electrolyzers.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Jason K. Phong, Christopher B. Cooper, Lukas Michalek, Yangju Lin, Yuya Nishio, Yuran Shi, Huaxin Gong, Julian A. Vigil, Jan Ilavsky, Ivan Kuzmenko, Zhenan Bao
Summary: Dynamic block copolymers (DBCPs) combine the phase separation of traditional block copolymers with the supramolecular self-assembly of periodic dynamic polymers, resulting in the spontaneous self-assembly of high aspect ratio nanofibers with well-ordered PEG and PDMS domains. DBCPs with a periodic block sequence exhibit superior properties compared to those with a random sequence, including delayed onset of terminal flow and higher ionic conductivity values.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Hong Kyu Lee, Yasaswini Oruganti, Jonghyeon Lee, Seunghee Han, Jihan Kim, Dohyun Moon, Min Kim, Dae-Woon Lim, Hoi Ri Moon
Summary: This study reports the moisture-triggered proton-conductivity switching behavior in Zn5FDC MOFs induced by the presence and absence of coordinating solvents, which illustrates the significant role of coordinating solvents in conductivity variation.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Bommaramoni Yadagiri, Sanjay Sandhu, Ashok Kumar Kaliamurthy, Francis Kwaku Asiam, Jongdeok Park, Appiagyei Ewusi Mensah, Jae-Joon Lee
Summary: The molecular engineering of the interface modulator between the perovskite and hole transporting material is crucial for achieving satisfactory performance and stability of perovskite solar cells. In this study, cruciform-shaped dual functional organic materials were employed as surface passivation and hole transporting interfacial layers in perovskite solar cells. The use of these materials significantly improved the power conversion efficiency of the solar cells.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Joaquin Martinez-Ortigosa, Reisel Millan, Jorge Simancas, Manuel Hernandez-Rodriguez, J. Alejandro Vidal-Moya, Jose L. Jorda, Charlotte Martineau-Corcos, Vincent Sarou-Kanian, Mercedes Boronat, Teresa Blasco, Fernando Rey
Summary: This study investigates the synthesis of all-silica RTH zeolites using triisopropyl(methyl)phosphonium as the organic SDA. The results show the formation of two distinct crystalline phases under different synthesis conditions, with fluoride bonding to different silicon sites. It demonstrates the possibility of controlling the placement of fluoride in RTH zeolites through synthesis conditions.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Luyao Zheng, Cong Liu, Wenbiao Zhang, Boxu Gao, Tianlan Yan, Yahong Zhang, Xiaoming Cao, Qingsheng Gao, Yi Tang
Summary: This study successfully improves the efficiency and stability of water splitting by constructing a heterostructured electrocatalyst. The catalyst shows extraordinary performance and could offer an effective approach for the sustainable production of hydrogen.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Carlos A. Campos-Roldan, Raphael Chattot, Frederic Pailloux, Andrea Zitolo, Jacques Roziere, Deborah J. Jones, Sara Cavaliere
Summary: This study systematically evaluated the hydrogen evolution/oxidation reactions on a series of Pt-rare earth nanoalloys in alkaline media, and identified the effect of the lanthanide contraction. The experimental results revealed that the chemical nature of the rare earth modulates the adsorption and mobility of oxygenated-species, enhancing the kinetics of the reactions.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Sara Frank, Mads Folkjaer, Mads L. N. Nielsen, Melissa J. Marks, Henrik S. Jeppesen, Marcel Ceccato, Simon J. L. Billinge, Jacopo Catalano, Nina Lock
Summary: This study investigates the thermal decomposition of ZIF-67 and its correlation with structural evolution and electrocatalytic performance. The researchers used in situ X-ray absorption spectroscopy and total scattering techniques to analyze the process. They found that disorder emerges at lower temperatures and that extending the pyrolysis process can result in materials with superior electrochemical properties.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Zi-Yang Zhang, Hao Tian, Han Jiao, Xin Wang, Lei Bian, Yuan Liu, Nithima Khaorapapong, Yusuke Yamauchi, Zhong-Li Wang
Summary: By constructing Cu-0-Cu+-NH2 composite interfaces with the assistance of SiO2, the electrochemical CO2 reduction reaction (CO2RR) achieves high Faraday efficiency and current density for C2+ production, improving the productivity of carbon cycle.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Ting Wang, Ruijuan Zhang, Pengda Zhai, Mingjie Li, Xinying Liu, Chaoxu Li
Summary: This study successfully exfoliated COFs using a simple electrochemical method, which resulted in improved photocatalytic performance for COFs and enriched the fabrication approach of COF exfoliation.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)