期刊
JOURNAL OF MATERIALS CHEMISTRY A
卷 3, 期 40, 页码 20408-20415出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ta03835a
关键词
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资金
- Iran National Science Foundation (INSF) [92024961]
- Iran Nano technology Initiative Council (INIC)
- Tarbiat Modares University
Two novel pillared metal-organic frameworks (MOFs) containing a urea-functional group are introduced. Herein, the urea functional group was incorporated into the MOF backbone by preparing a urea-ditopic ligand. These frameworks (TMU-18 and TMU-19) were fabricated using the synthesized urea-containing ligand, 4,40-bipyridine (bipy) and 1,2-bis(4-pyridyl) ethane (bpe), and using zinc nitrate as the metal source. Subsequently, TMU-18 and TMU-19 were characterized by X-ray diffraction, IR spectroscopy, elemental analysis, scanning electron microscopy (SEM) and thermogravimetric analysis. Furthermore, their potential efficiency as organocatalysts was evaluated in the regioselective methanolysis of epoxides.
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