Article
Energy & Fuels
Negin Beiraghdar, Hossein Dehghani, Malihe Afrooz
Summary: A low-cost and straightforward method was reported for modifying polysulfide electrolyte using amine additives to enhance CdS/CdSe QDSSCs performance. The addition of thiourea in the electrolyte solution played a crucial role in forming a molecular complex, increasing electron lifetime, J(SC), and improving PCE value.
Review
Chemistry, Physical
Akash S. Rasal, Sudesh Yadav, Anil A. Kashale, Ali Altaee, Jia-Yaw Chang
Summary: This review discusses the factors influencing the performance stability of QDSSCs and provides insights into the mechanisms causing degraded performances. It also presents cutting-edge strategies for improving the overall performance stability of QDSSCs.
Article
Electrochemistry
Akash S. Rasal, Chiranjeevi Korupalli, Girum Getachew, Tzung-Han Chou, Ting-Ying Lee, Anil V. Ghule, Jia-Yaw Chang
Summary: The study introduces novel nature-inspired biopolymer polydopamine (PDA)-based additives to polysulfide electrolytes, achieving efficient and stable quantum dot-sensitized solar cells (QDSSCs). The PDA-based additives not only boost conversion efficiencies but also greatly enhance device performance stability, possibly due to the antioxidative property of PDA neutralizing light-induced radicals.
ELECTROCHIMICA ACTA
(2021)
Article
Materials Science, Ceramics
Z. Sherafati Tabarestani, M. Samadpour
Summary: Three-dimensional silica mesh structures are prepared to enhance the performance and stability of quantum dot sensitized solar cells. The improved light scattering properties of the meshed structures lead to increased current density and efficiency of the cells. The silica mesh reduces recombination rate and improves the efficiency of the cells. Moreover, it also reduces the deleterious effect of the electrolyte on the semiconductor layers, resulting in improved stability of the cells.
CERAMICS INTERNATIONAL
(2022)
Article
Nanoscience & Nanotechnology
Yukai Ma, Yunong Zhang, Ming Liu, Tongliga Han, Yanlai Wang, Xiaojing Wang
Summary: In this study, Zn-CuInS2 and CuInS2 quantum dots were synthesized by heat injection method for their application as photosensitizers in quantum dot sensitized solar cells. It was found that Zn doping expands the optical absorption range, enhances luminescence intensity, and improves electron injection efficiency. The Zn-CuInS2 QDSCs exhibit high conversion efficiency and short circuit current density under AM 1.5G illumination.
ADVANCED COMPOSITES AND HYBRID MATERIALS
(2022)
Article
Engineering, Multidisciplinary
Akash S. Rasal, Ting-Wei Chang, Chiranjeevi Korupalli, Jia-Yaw Chang
Summary: This study successfully synthesized Cu2-xSySe1-y alloyed semiconductors film with tunable crystal structures, compositions, and morphologies as counter electrode materials, demonstrating excellent stability and high conversion efficiency in photovoltaic applications.
COMPOSITES PART B-ENGINEERING
(2022)
Article
Materials Science, Multidisciplinary
Zhuoyin Peng, Wen Luo, Chengtang Long, Yue Wang, Yilong Fu
Summary: In this study, a CuxS/GO composite hole transport layer is used to modulate the charge transfer efficiency of quantum dot-sensitized solar cells. The introduction of the CuxS/GO composite layer significantly reduces the normalized PL intensity of TiO2/CuInS2 photo-electrodes, indicating excellent charge separation properties. The charge recombination traps are also reduced under the CuxS/GO composite layer, leading to an effective improvement in the charge transfer efficiency of the solar cells. As a result, TiO2/CuInS2 quantum dot-sensitized solar cells with the CuxS/GO composite layer exhibit higher V-oc, FF and J(sc) values, resulting in an enhancement of the photovoltaic conversion efficiency from 4.85% to 6.07%.
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING
(2023)
Review
Chemistry, Physical
Layla Haythoor Kharboot, Nor Akmal Fadil, Tuty Asma Abu Bakar, Abdillah Sani Mohd Najib, Norhuda Hidayah Nordin, Habibah Ghazali
Summary: Third-generation solar cells, such as dye-sensitized solar cells and quantum dot-sensitized solar cells, require counter electrodes (CEs) for their functionality. Platinum-based CEs are dominant but expensive, thus alternative materials like transition metal chalcogenides (TMCs) and transition metal dichalcogenides (TMDs) have been explored. This study provides a comprehensive review of the major components and working principles of these solar cells, and evaluates the performance efficiencies resulting from TMS-based CEs compared to Pt-based CEs.
Article
Chemistry, Inorganic & Nuclear
Lan Zhou, Hong Ling Ren, Chun Qin Yang, Ya Xue Wu, Bin Bin Jin
Summary: By using the SILAR method, ATO porous matrix film-supported CuS composites were constructed on a fluorine-doped tin oxide glass substrate, showing excellent electrocatalytic activity. Through optimizing the deposition cycles, a stable efficiency was achieved while improving the conductivity.
INORGANIC CHEMISTRY COMMUNICATIONS
(2022)
Article
Energy & Fuels
S. Akhil, J. Kusuma, S. Akash, R. Geetha Balakrishna
Summary: This study explores the use of Lanthanum Strontium Manganite as an electrolyte in Quantum dot sensitized solar cells, which shows potential in improving device performance and stability by reducing back transfer of electrons. There is a possibility of completely replacing liquid electrolytes with ceramics in the future.
Article
Energy & Fuels
Tamal Dey, Arup Ghorai, Soumen Das, Samit K. Ray
Summary: The choice of solvent used in the synthesis of nitrogen-doped graphene quantum dots (N-GQDs) significantly affects the photovoltaic performance of quantum dot sensitized solar cells (QDSSC). Switching to aprotic solvent DMF enhances nitrogen units in the graphene quantum dots framework, improving carrier density and transport properties, and resulting in better photovoltaic performance for QDSSC.
Article
Chemistry, Physical
Meitong Chu, Zhonglin Du, Yanying Zhang, Lin Li, Shujie Jiao, Fahad Azad, Shichen Su
Summary: In this study, a graphene/Cu2-xSe composite material was prepared and studied for its photovoltaic and electrochemical properties. By optimizing the ratio of GR:Cu2-xSe and sintering temperature, the QDSCs based on the optimized GR/Cu2-xSe composite CE showed a significant improvement in cell performance compared to other types of CEs, with a PCE of 6.66%. The enhanced performance of the composite CE was attributed to the combination of high catalytic activity of Cu2-xSe nanoparticles and good conductivity of graphene, suggesting that GR/Cu2-xSe composite CE could be a potential candidate for high efficiency QDSCs.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Nanoscience & Nanotechnology
Mengqi Cui, Na Li, Yuying Wang, Yuting Li, Xia Tian, Xingchen Zhang, Wenting Wang, Zhongmin Liu, Qikun Rong, Xingsen Gao, Guofu Zhou, Li Nian
Summary: This study demonstrates an effective and simple approach to optimize the performance of both cathode and anode interlayers in organic solar cells by doping them with 4-heptyl-4'-cyanobiphenyl (7CB). Devices with 7CB-doped interlayers show increased short-circuit current density, fill factor, and power conversion efficiency compared to undoped interlayers, regardless of whether it is the anode or cathode interlayer, which is a rare phenomenon in the field of interlayer modification.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Chemistry, Physical
Wei Wang, Yiling Xie, Fangfang He, Yuan Wang, Weinan Xue, Yan Li
Summary: In quantum dot-based solar cells (QDSCs), the balance between QD loading and TiO2 film thickness significantly affects the performance. A relatively thin photoanode prepared by a cationic surfactant-assisted multiple deposition procedure achieved a high QD loading comparable to that of the commonly used thick photoanode. Under optimized conditions, the Zn-Cu-In-Se and Zn-Cu-In-S based QDSCs showed a comparable power conversion efficiency (PCE) to those with significantly thicker photoanodes (over 25.0 μm).
GREEN ENERGY & ENVIRONMENT
(2023)
Article
Electrochemistry
Di Zhang, Sidong Zhang, Yanyan Fang, Dongmei Xie, Xiaowen Zhou, Yuan Lin
Summary: Introducing bifunctional linkers between TiO2 electrodes and quantum dots was an effective approach for the preparation of quantum dot-sensitized solar cells. Three types of linkers were studied, with phenyl MBA-TiO2 electrodes achieving the highest Cd content and PCE. The modified TiO2 electrodes showed lower electron recombination rates and higher efficiency, demonstrating the importance of linker selection for QDSCs design and optimization.
ELECTROCHIMICA ACTA
(2021)
Article
Chemistry, Multidisciplinary
Namyoung Ahn, Young-Shin Park, Clement Livache, Jun Du, Kivanc Gungor, Jaehoon Kim, Victor I. Klimov
Summary: Laser diodes based on solution-processable materials have immense potential in various technologies. However, there have been challenges in achieving QD laser diodes, including rapid nonradiative decay and device degradation. In this study, we overcome these challenges and demonstrate optically excited lasing from fully functional high-current density electroluminescent devices.
ADVANCED MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Shan He, Jun Du, Wenfei Liang, Boyu Zhang, Guijie Liang, Kaifeng Wu
Summary: Thermally activated delayed photoluminescence (TADPL) is an exotic mechanism observed in molecule-functionalized semiconductor nanocrystals, which allows for energy harvesting from dark molecular triplets and controllable, long-lived photoluminescence. Despite successful coverage of the visible spectrum, TADPL in nanocrystals is less efficient compared to thermally activated delayed fluorescence (TADF) molecules. In this study, bright, near-infrared TADPL was achieved in lead-free CuInSe2 nanocrystals functionalized with carboxylated tetracene ligands, by efficient triplet energy transfer from nanocrystals to ligands and subsequent thermally activated reverse energy transfer.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Engineering, Environmental
Lingcong Li, Ruike Zhang, Zhujie Wu, Yao Wang, Jin Hong, Huashang Rao, Zhenxiao Pan, Xinhua Zhong
Summary: The preparation of high-efficiency perovskite solar cells in ambient air environment is challenging. In this study, a simple component engineering strategy is proposed to regulate the crystallization process of perovskite film, leading to improved crystallinity, reduced defect state density, and suppressed non-radiative recombination processes. The efficiency of the carbon-based perovskite solar cells reached a record high.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Engineering, Environmental
Jianxin Zhang, Guizhi Zhang, Yongyu Liao, Zhenxiao Pan, Huashang Rao, Xinhua Zhong
Summary: In this study, a novel hybrid hole conductor, Poly-3-hexylthiophene - CsPbI3 quantum dots (P-QD), was used to improve hole extraction in CsPbI2Br C-PSCs. The P-QD hybrid hole conductor effectively improved hole extraction by aligning perovskite/carbon energy-level and extending the optical response range of CsPbI2Br solar cells, resulting in an increased power conversion efficiency from 13.49% to 15.04%. This strategy provides a new approach for the construction of hole transport layers in carbon-based perovskite solar cells.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Optics
Wenfei Liang, Chengming Nie, Jun Du, Yaoyao Han, Guohui Zhao, Fan Yang, Guijie Liang, Kaifeng Wu
Summary: Researchers have used zinc-doped CuInSe2 nanocrystals as a low-cost and non-toxic alternative to lead chalcogenides for near-infrared upconversion. Achieving upconversion to yellow with an external quantum efficiency of 16.7%, this system can be combined with photoredox catalysis for efficient near-infrared-driven organic synthesis and polymerization, overcoming the issue of reabsorption loss. Additionally, the wide light absorption range of these nanocrystals enables rapid reactions under indoor sunlight, extending the potential of "solar synthesis" in the near-infrared spectrum.
Article
Chemistry, Physical
Cuiting Kang, Shuaihang Xu, Huashang Rao, Zhenxiao Pan, Xinhua Zhong
Summary: A strategy for constructing an all-inorganic 2D/3D CsPb2I4Br/CsPbI2Br bulk heterojunction (BHJ) by in situ reaction of excess PbI2 in a precursor solution with CsPbI2Br during annealing is proposed. The formed 2D/3D BHJ effectively passivates defects in 3D CsPbI2Br and reduces nonradiative recombination loss in carbon electrode-based perovskite solar cells (C-PSCs). The optimized C-PSCs achieve an open-circuit voltage of 1.32 V and an efficiency of 15.25%, which are the best results for CsPbI2Br-based C-PSCs.
ACS ENERGY LETTERS
(2023)
Article
Chemistry, Physical
Zhengyan Zhang, Han Song, Wenran Wang, Huashang Rao, Yueping Fang, Zhenxiao Pan, Xinhua Zhong
Summary: A ligand design strategy using mercaptopropionic acid (MPA) and inorganic ligands (ILs) as dual ligands on the surface of quantum dots (QDs) is developed to enhance the loading amount and optoelectronic performance of QD sensitizers. The ILs not only facilitate QD loading but also reduce interdot repulsion and form dense QD layers, while the pseudohalide SCN- has a passivation effect on QD surfaces and suppresses defect trap states. As a result, QDSCs based on dual SCN/MPA ligands achieve a certified efficiency of 16.10%, a new record for liquid junction QD solar cells.
ACS ENERGY LETTERS
(2023)
Article
Chemistry, Multidisciplinary
Yongyu Liao, Jianxin Zhang, Wenran Wang, Zechao Yang, Rong Huang, Jiage Lin, Lei Che, Guoying Yang, Zhenxiao Pan, Huashang Rao, Xinhua Zhong
Summary: Surface molecular passivation is an effective strategy to reduce defect-assisted recombination and nonradiative recombination loss in perovskite solar cells (PSCs). However, most passivating molecules bind weakly to the perovskite surface, resulting in weak passivation effects. In carbon-based perovskite solar cells (C-PSCs), the molecular passivation effect is more susceptible to disturbance during the preparation of carbon electrodes. In this study, a bidentate ligand 2,2'-Bipyridine (2Bipy) is used to passivate surface defects of CsPbI2.6Br0.4 perovskite films. The results show that 2Bipy exhibits a stronger chelation effect and achieves better passivation performance compared to monodentate pyridine (Py). As a result, the efficiency of C-PSCs is significantly improved, setting a new record efficiency for hole transport material-free inorganic C-PSCs.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Ruike Zhang, Lingcong Li, Wenran Wang, Zhujie Wu, Yao Wang, Jin Hong, Huashang Rao, Zhenxiao Pan, Xinhua Zhong
Summary: Researchers reported a new method for fabricating wide-bandgap perovskite solar cells without acid treatment. Formamidine/cesium (FA/Cs) as an additive can effectively control the crystallization process of perovskite films, improving the crystallinity and efficiency of the solar cells.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Jianxin Zhang, Guizhi Zhang, Pei-Yang Su, Rong Huang, Jiage Lin, Wenran Wang, Zhenxiao Pan, Huashang Rao, Xinhua Zhong
Summary: Defects in perovskite can be effectively passivated by choline halide (ChX), which binds with charged point defects. We found that ChI can react with CsPbI3 to form a novel crystal phase of one-dimensional (1D) ChPbI(3), which improves the photoluminescence lifetime and stability of the CsPbI3 film. The CsPbI3-based carbon-based solar cells achieved high efficiencies and set new records in hole transport material-free inorganic solar cells.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Multidisciplinary
Yao Wang, Lingcong Li, Zhujie Wu, Ruike Zhang, Jin Hong, Jianxin Zhang, Huashang Rao, Zhenxiao Pan, Xinhua Zhong
Summary: A self-driven prenucleation strategy using formamide as the co-solvent is proposed to achieve fast nucleation and improve the crystalline quality of perovskite film.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Multidisciplinary
Zhujie Wu, Yao Wang, Lingcong Li, Ruike Zhang, Jin Hong, Rong Huang, Lei Che, Guoying Yang, Huashang Rao, Zhenxiao Pan, Xinhua Zhong
Summary: In this study, a mild continuous pH control strategy using urea as a weak organic base was proposed to regulate the hydrolysis process of TiCl4 post-treatment. This strategy facilitated the formation of an anatase-dominated TiO2 surface layer on the mesoporous TiO2, leading to reduced defect density and improved charge extraction efficiency in perovskite solar cells (PSCs). The fabricated carbon electrode-based PSCs (C-PSCs) achieved an efficiency of 18.08%, the highest among C-PSCs based on wide-bandgap perovskites.
Article
Materials Science, Multidisciplinary
Guizhi Zhang, Jianxin Zhang, Zhenxiao Pan, Huashang Rao, Xinhua Zhong
Summary: Researchers synthesized a carbon nanotube/poly(3-hexylthiophene) (CNT/P3HT) composite as a hole transport material to construct state-of-the-art carbon-based perovskite solar cells (C-PSCs). The CNT in the composite provides a high-speed channel for hole transmission, lowering charge transmission impedance and improving hole extraction efficiency. Using this composite, CsPbI2Br C-PSCs achieved an increase in open-circuit voltage from 1.233 to 1.355 V and power conversion efficiency from 13.29% to 15.56%, setting a new record for all-inorganic perovskite C-PSCs.
SCIENCE CHINA-MATERIALS
(2023)
Article
Biotechnology & Applied Microbiology
Qinghong Guo, Xuefang Guo, Nuo Ji, Bang Shen, Xinhua Zhong, Lihua Xiao, Yaoyu Feng, Ningbo Xia
Summary: Toxoplasma gondii is a widespread pathogen that infects various warm-blooded animals, including humans, leading to significant socioeconomic and healthcare burdens. Despite the lack of an ideal toxoplasmosis vaccine, targeting key pathways in the parasite's metabolism shows promise for new antiparasitic strategies.
MICROBIAL BIOTECHNOLOGY
(2023)
Article
Chemistry, Physical
Wei Wang, Yiling Xie, Fangfang He, Yuan Wang, Weinan Xue, Yan Li
Summary: In quantum dot-based solar cells (QDSCs), the balance between QD loading and TiO2 film thickness significantly affects the performance. A relatively thin photoanode prepared by a cationic surfactant-assisted multiple deposition procedure achieved a high QD loading comparable to that of the commonly used thick photoanode. Under optimized conditions, the Zn-Cu-In-Se and Zn-Cu-In-S based QDSCs showed a comparable power conversion efficiency (PCE) to those with significantly thicker photoanodes (over 25.0 μm).
GREEN ENERGY & ENVIRONMENT
(2023)
Article
Chemistry, Physical
Mei Gui Vanessa Wee, Amutha Chinnappan, Runxin Shang, Poh Seng Lee, Seeram Ramakrishna
Summary: Cooling processes, from residences to industries, require a lot of energy and are essential. This study introduces MIL-101(Cr), a new desiccant, to heat exchangers for more efficient cooling. By improving the synthesis method and using a special binder, the MIL-101(Cr)-coated heat exchanger shows improved water uptake capacity and lower regeneration temperature.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Ao Zhen, Guanyu Zhang, Ao Wang, Feng Luo, Jiehua Li, Hong Tan, Zhen Li
Summary: In this study, a solvent-free microemulsion method was used to synthesize waterborne polyurethane (WPU) material with high retention of mechanical properties and satisfactory water absorption rates. The material showed excellent biocompatibility and has broad application potential in the field of biomedicine.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Review
Chemistry, Physical
Wensong Ge, Rui Wang, Xiaoyang Zhu, Houchao Zhang, Luanfa Sun, Fei Wang, Hongke Li, Zhenghao Li, Xinyi Du, Huangyu Chen, Fan Zhang, Huifa Shi, Huiqiang Hu, Yongming Xi, Jiankang He, Liang Hu, Hongbo Lan
Summary: This paper reviews the research on the surface tension of eutectic gallium-indium alloys (EGaIn) in the field of stretchable electronics. It covers the principles of oxide layer formation, factors influencing surface tension, and methods for surface modification of liquid metals. The paper also discusses the applications of EGaIn surface modification in different fields and highlights the challenges still faced and the future outlook.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Review
Chemistry, Physical
Xiang Song, Lianghao Jia, Zhengen Wei, Tao Xiang, Shaobing Zhou
Summary: This paper provides an overview of the application, preparation, and role of biomimetic structures in solar evaporators with improved evaporation rate and lifetime.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Wei Yuan, Qian Deng, Dong Pan, Xiang An, Canyang Zhao, Wenjun Su, Zhengmin He, Qiang Sun, Ran Ang
Summary: Optimizing the performance of n-type PbTe thermoelectric materials is crucial for practical applications. Dynamic doping has emerged as an effective method to improve the performance of n-type PbTe by optimizing the carrier concentration. This study demonstrates the significance of Mn alloying in enhancing the performance of Ag-doped n-type PbTe by creating a hierarchical structure to suppress thermal transport and improving the Seebeck coefficient.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Review
Chemistry, Physical
Xiaoyan Wang, Meiqi Geng, Shengjun Sun, Qian Xiang, Shiyuan Dong, Kai Dong, Yongchao Yao, Yan Wang, Yingchun Yang, Yongsong Luo, Dongdong Zheng, Qian Liu, Jianming Hu, Qian Wu, Xuping Sun, Bo Tang
Summary: This review provides a comprehensive analysis of the progress and challenges in the field of bifunctional electrocatalysts and efficient electrolyzers for seawater splitting. It summarizes recent advancements and proposes future perspectives for highly efficient bifunctional electrocatalysts and electrolyzers.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Jason K. Phong, Christopher B. Cooper, Lukas Michalek, Yangju Lin, Yuya Nishio, Yuran Shi, Huaxin Gong, Julian A. Vigil, Jan Ilavsky, Ivan Kuzmenko, Zhenan Bao
Summary: Dynamic block copolymers (DBCPs) combine the phase separation of traditional block copolymers with the supramolecular self-assembly of periodic dynamic polymers, resulting in the spontaneous self-assembly of high aspect ratio nanofibers with well-ordered PEG and PDMS domains. DBCPs with a periodic block sequence exhibit superior properties compared to those with a random sequence, including delayed onset of terminal flow and higher ionic conductivity values.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Hong Kyu Lee, Yasaswini Oruganti, Jonghyeon Lee, Seunghee Han, Jihan Kim, Dohyun Moon, Min Kim, Dae-Woon Lim, Hoi Ri Moon
Summary: This study reports the moisture-triggered proton-conductivity switching behavior in Zn5FDC MOFs induced by the presence and absence of coordinating solvents, which illustrates the significant role of coordinating solvents in conductivity variation.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Bommaramoni Yadagiri, Sanjay Sandhu, Ashok Kumar Kaliamurthy, Francis Kwaku Asiam, Jongdeok Park, Appiagyei Ewusi Mensah, Jae-Joon Lee
Summary: The molecular engineering of the interface modulator between the perovskite and hole transporting material is crucial for achieving satisfactory performance and stability of perovskite solar cells. In this study, cruciform-shaped dual functional organic materials were employed as surface passivation and hole transporting interfacial layers in perovskite solar cells. The use of these materials significantly improved the power conversion efficiency of the solar cells.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Joaquin Martinez-Ortigosa, Reisel Millan, Jorge Simancas, Manuel Hernandez-Rodriguez, J. Alejandro Vidal-Moya, Jose L. Jorda, Charlotte Martineau-Corcos, Vincent Sarou-Kanian, Mercedes Boronat, Teresa Blasco, Fernando Rey
Summary: This study investigates the synthesis of all-silica RTH zeolites using triisopropyl(methyl)phosphonium as the organic SDA. The results show the formation of two distinct crystalline phases under different synthesis conditions, with fluoride bonding to different silicon sites. It demonstrates the possibility of controlling the placement of fluoride in RTH zeolites through synthesis conditions.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Luyao Zheng, Cong Liu, Wenbiao Zhang, Boxu Gao, Tianlan Yan, Yahong Zhang, Xiaoming Cao, Qingsheng Gao, Yi Tang
Summary: This study successfully improves the efficiency and stability of water splitting by constructing a heterostructured electrocatalyst. The catalyst shows extraordinary performance and could offer an effective approach for the sustainable production of hydrogen.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Carlos A. Campos-Roldan, Raphael Chattot, Frederic Pailloux, Andrea Zitolo, Jacques Roziere, Deborah J. Jones, Sara Cavaliere
Summary: This study systematically evaluated the hydrogen evolution/oxidation reactions on a series of Pt-rare earth nanoalloys in alkaline media, and identified the effect of the lanthanide contraction. The experimental results revealed that the chemical nature of the rare earth modulates the adsorption and mobility of oxygenated-species, enhancing the kinetics of the reactions.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Sara Frank, Mads Folkjaer, Mads L. N. Nielsen, Melissa J. Marks, Henrik S. Jeppesen, Marcel Ceccato, Simon J. L. Billinge, Jacopo Catalano, Nina Lock
Summary: This study investigates the thermal decomposition of ZIF-67 and its correlation with structural evolution and electrocatalytic performance. The researchers used in situ X-ray absorption spectroscopy and total scattering techniques to analyze the process. They found that disorder emerges at lower temperatures and that extending the pyrolysis process can result in materials with superior electrochemical properties.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Zi-Yang Zhang, Hao Tian, Han Jiao, Xin Wang, Lei Bian, Yuan Liu, Nithima Khaorapapong, Yusuke Yamauchi, Zhong-Li Wang
Summary: By constructing Cu-0-Cu+-NH2 composite interfaces with the assistance of SiO2, the electrochemical CO2 reduction reaction (CO2RR) achieves high Faraday efficiency and current density for C2+ production, improving the productivity of carbon cycle.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Ting Wang, Ruijuan Zhang, Pengda Zhai, Mingjie Li, Xinying Liu, Chaoxu Li
Summary: This study successfully exfoliated COFs using a simple electrochemical method, which resulted in improved photocatalytic performance for COFs and enriched the fabrication approach of COF exfoliation.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)