Review
Engineering, Biomedical
Eduardo Anaya-Plaza, Ahmed Shaukat, Inka Lehtonen, Mauri A. Kostiainen
Summary: The strategy of combining biomolecules and synthetic components to develop biohybrids is becoming increasingly popular for preparing highly customized and biocompatible functional materials, allowing the excellent properties of carbon nanotubes (CNTs) to be applied to biomedical applications. The resulting well-defined composites of CNTs conjugated with relevant biomolecules enable the exploitation of nanoscale properties at the micro- and macroscale, with potential applications in tissue engineering, sensors, and wearable electronics. This review presents the underlying chemistry behind the CNT-based biohybrid materials and discusses the future directions of the field.
ADVANCED HEALTHCARE MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Weiming Huang, Wanmin Chen, Qixia Bai, Zhe Zhang, Min Feng, Zhiping Zheng
Summary: This study demonstrates the rational assembly of high-nuclearity lanthanide hydroxide clusters, which is of great significance for the realization of complex molecular materials and functions.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Chemistry, Physical
Yurong Zhao, Hao Qi, Limin Zhang, Chunyong He, Feng Wei, Dong Wang, Jie Li, Kai Qi, Xuzhi Hu, Jiqian Wang, Yubin Ke, Chunqiu Zhang, Jian R. Lu, Hai Xu
Summary: This study investigates the morphology transition of peptide self-assembly and finds that shifting the position of the terminal residue can achieve the transition from nanofibers to nanotubes. The underlying mechanism is revealed, and it is found that the formation of giant nanotubes with a bilayer shell structure is promoted by inter-molecular C-terminal H-bonding. This morphological transformation method is applicable to other analogues and provides a convenient approach for predicting peptide nanostructures.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2023)
Article
Chemistry, Multidisciplinary
Fanyi Min, Zhao-Yang Zhang, Zhiyuan Qu, Jie Gao, Xiaosong Shi, Haoran Long, Yixin Li, Shengnan Chen, Dongfang Dong, Yuanping Yi, Lang Jiang, Juehan Yang, Tao Li, Yali Qiao, Yanlin Song
Summary: Humidity plays a critical role in molecular assembly, forming microscale liquid confined space under high humidity and nanoscale liquid confined space under low humidity. The differences in surface wettability and adhesion are important. The study reveals that flat patterns with thermodynamically ordered structure and sharp patterns with dynamically disordered structure show different photoisomerization behaviors and photoresponsiveness. The sharp pattern with disordered structure has higher conductivity than the flat pattern with layered ordered structure due to different electronic transport mechanisms. This work provides a new approach for controlling the morphology and function of molecular patterns through manipulating molecular self-assembly.
Article
Engineering, Chemical
Surita Basu, Prabir Patra, Jayati Sarkar
Summary: In this article, the authors demonstrate the influence of the instability of a polymeric thin film on the self-assembly and arrangement of carbon nanotube nanoparticles. The interplay of different forces, such as centrifugal, dewetting, Marangoni, and electrostatic forces, leads to the formation of circular ring-like structures. The study highlights the role of dewetting dynamics and electrostatic repulsion in the formation of these ring structures. Additionally, the authors observe the formation of nano-scratches on the polymeric surface driven by Marangoni force. The bending of carbon nanotubes into circular rings is found to be an energetically favored self-organization process. The assembled carbon nanotubes exhibit interconnected relief structures when the underlying dewetted polystyrene surface acts as a template. The circular rings of carbon nanotubes formed by the dewetting of the mixture method can be utilized for the detection of trace amounts of oil in an oil-water mixture through selective adsorption. The self-assembly of carbon nanotubes into ring structures is concentration-dependent, and above a certain concentration, random bundle/blob structures are observed.
CHEMICAL ENGINEERING SCIENCE
(2022)
Article
Chemistry, Multidisciplinary
Chun-Li Luo, Jun-Yi Jiao, Xing-Jie Su, Lin-Xin Zheng, Wei-Guo Yan, Dong-Zhou Zhong
Summary: Researchers developed interlinked microcone resistive sensors using polydimethylsiloxane (PDMS) nanocone arrays and self-assembled two-dimensional carbon nanotubes (CNTs) networks. These sensors can detect external pressure with high sensitivity and stability in a wide range of pressures, making them promising for monitoring human motion and wearable devices.
Article
Chemistry, Physical
Wenchao Yang, Yicheng Zhou, Biao Jin, Xin Qi, Bin Cai, Qiuxiang Yin, Jim Pfaendtner, James J. De Yoreo, Chun-Long Chen
Summary: In the biological environment, mineral crystals controlled by biomacromolecules exhibit intricate structures and superior mechanical properties. Through the design of peptoids with strong binding to silica, self-assembled peptoid fibers can mimic the biocatalytic and templating functions of silicatein filaments, resulting in the formation of silica fibers. The presence of amino groups is crucial for nucleation of silica on self-assembled peptoid nanofibers. The formation of silica shell on peptoid fibers greatly enhances the mechanical property of hydrogel materials.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2023)
Article
Nanoscience & Nanotechnology
Bo Song, Kun Cai, Jiao Shi, Qing-Hua Qin
Summary: This study reveals the feasibility of fabricating graphene nanotubes (GNTs) by self-assembling a monolayer graphene ribbon on a carbon nanotube (CNT) and explores the mechanism of temperature dependence in the self-assembly process. Different types, lengths, and radii of GNTs can be obtained by controlling the geometry of the graphene ribbon and temperature.
Article
Chemistry, Physical
Shuai Ren, Shiyong Gao, Huiqing Lu, Ping Rong, Xiangyu Zhang, Lin Li, Shujie Jiao, Dongbo Wang, Yong Zhang, Jinzhong Wang
Summary: Large-scale Bi2O3 nanotubes arrays were successfully synthesized using ZnO nanorods template and applied in the construction of a UV photodetector. The detector exhibited high current density, fast response time, and good stability.
APPLIED SURFACE SCIENCE
(2022)
Review
Chemistry, Applied
Qingfu Ban, Yaochen Zheng, Yusheng Qin, Jie Kong
Summary: Mesoporous nanospheres are important in energy, catalysis, and sensor technology due to their multilevel architectures and tunable meso-structures. They can be obtained through aqueous polymer self-assembly and co-assembly-driven nanocomposite formation techniques using amphiphilic block copolymers and low-molecular-weight surfactants as soft templates.
MICROPOROUS AND MESOPOROUS MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Nadezda Prochukhan, Andrew Selkirk, Ross Lundy, Elsa C. Giraud, Tandra Ghoshal, Clive Downing, Michael A. Morris
Summary: A room-temperature strategy for fabricating vertical silicon nanotube arrays derived from a toroidal micelle pattern via water vapor-induced block copolymer self-assembly mechanism is presented. The simplicity of the technique and the versatility of resulting metal structures show the potential applicability of such room-temperature synthesis routes.
Review
Chemistry, Multidisciplinary
Jake L. Greenfield, Jonathan R. Nitschke
Summary: Metal-containing polymers, or metallopolymers, have diverse applications in various fields. The self-assembly of metal-templated subcomponents allows the formation of complex structures. The control of parameters in metallopolymers can influence their growth behavior and properties, potentially meeting specific application requirements.
ACCOUNTS OF CHEMICAL RESEARCH
(2022)
Article
Materials Science, Multidisciplinary
Hidemasa Negoro, Hiroshi Sugimoto, Tatsuki Hinamoto, Minoru Fujii
Summary: A solution-based bottom-up process is developed to produce one- and two-dimensional arrays of densely packed spherical nanoparticles (NPs) of crystalline silicon (Si), which have the lowest order Mie resonance in the visible range. The arrays are formed using a template-assisted self-assembly method and transferred to an arbitrary substrate. The proper formation of Si NP arrays is demonstrated through polarization-resolved scattering spectra measurements and numerical simulations. The results show strong modification of scattering spectra due to near-field coupling of the electric dipole (ED) modes and the Kerker effect.
ADVANCED OPTICAL MATERIALS
(2022)
Article
Chemistry, Physical
Xinyu Liao, Prashant K. Purohit
Summary: Proteins self-assembly on lipid membranes is crucial for various cell biology processes, and the attractive force leading to self-assembly is mediated by membrane thickness interactions. The time scale for two inclusions to coalesce has been calculated as a function of initial distance, showing that two inclusions separated by around hundred nanometers will coalesce in hundreds of milliseconds regardless of shape. Computational strategies in this study provide efficient methods to explore protein self-assembly kinetics on lipid membranes.
Article
Chemistry, Multidisciplinary
Guanying Li, Xunwu Hu, Pingping Nie, Dingze Mang, Shi Jiao, Shijin Zhang, Sona Rani Roy, Sachie Yukawa, Shunsuke Asahina, Hiroaki Sugasawa, William Cortes, Zhaocai Zhou, Ye Zhang
Summary: The study introduced a molecular self-assembly technology that selectively halts cancer cell proliferation by inactivating the oncoprotein YAP. This technology targets the accumulation of ALPP and utilizes nanostructures specifically on lipid rafts of ovarian cancer cells to exert potent anti-proliferative effects.
Article
Chemistry, Physical
Yuting Wu, Long Yang, Bo Wu, Jie Li, Binyao Liu, Gaili Ke, Faqin Dong, Yong Zhou, Huichao He
Summary: The catalytic role of β-MnO2 for the oxidative coupling of 2-naphthols into 1,1'-bi-2-naphthols was systematically investigated in both dark and under visible-light irradiation. Results showed that β-MnO2 catalysis had optimal performance, with high selectivity and stability even after multiple uses. This study provided a comprehensive understanding of the catalytic mechanism of MnO2 for this reaction.
Article
Chemistry, Multidisciplinary
Liang Li, Yong Yang, Liuqing Yang, Xiaoyong Wang, Yong Zhou, Zhigang Zou
Summary: The 3D hierarchical InVO4/Ti3C2Tx heterosystem, with optimized 2D/2D interface interaction, demonstrates improved photocatalytic CO2 conversion performance.
Article
Chemistry, Multidisciplinary
Qiutong Han, Xiaowan Bai, Jingming Chen, Shengnan Feng, Wa Gao, Wenguang Tu, Xiaoyong Wang, Jinlan Wang, Bi Jia, Qing Shen, Yong Zhou, Zhigang Zou
Summary: The study successfully fabricated the unique InVO4 mesocrystal superstructure and proposed its growth mechanism. Measurements of single-particle surface photovoltage and confocal fluorescence spectroscopy demonstrated significant electron transfer characteristics of the mesocrystal superstructure. This superstructure greatly influences the photocatalytic performance of InVO4.
ADVANCED MATERIALS
(2021)
Article
Multidisciplinary Sciences
Wa Gao, Shi Li, Huichao He, Xiaoning Li, Zhenxiang Cheng, Yong Yang, Jinlan Wang, Qing Shen, Xiaoyong Wang, Yujie Xiong, Yong Zhou, Zhigang Zou
Summary: Artificial photosynthesis, converting CO2 into hydrocarbon fuels using light energy, is a promising approach to address global warming and energy-supply challenges. By engineering sulfur defects, the CO2 photoreduction pathway can be altered to increase ethene production.
NATURE COMMUNICATIONS
(2021)
Article
Chemistry, Physical
Jiajia Wu, Lijun Xiong, Yingjie Hu, Yong Yang, Xiaoyue Zhang, Tianyu Wang, Zheng Tang, Aiwu Sun, Yong Zhou, Jinyou Shen, Zhigang Zou
Summary: The study developed a hierarchical erythroid-like BiVO4/hm-C4N3 direct Z-Scheme heterojunction, achieving overall photocatalytic CO2 and H2O conversion to CO and O2 without any sacrificial reagent and co-catalyst. The optimized catalyst demonstrated high CO production rate and selectivity.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2021)
Article
Chemistry, Physical
Liyuan Long, Gangyang Lv, Qiutong Han, Xianchen Wu, Yu Qian, Dunhui Wang, Yong Zhou, Zhigang Zou
Summary: The research presents a well-designed alpha-Fe2O3@CdS bilayer heterostructure with effective interfacial electronic coupling, enhanced photoinduced charge separation, and extended photoelectron lifetime for efficient photocatalytic CO2 conversion. The Z-scheme charge transfer path and dynamics achieved by favorable internal built-in electric field at the heterointerface contribute to the excellent performance. The work provides insights into the construction and interface electronic mechanism of direct Z-scheme heterostructures for future solar energy conversion applications.
JOURNAL OF PHYSICAL CHEMISTRY C
(2021)
Article
Chemistry, Physical
Heng Zhu, Shuyu Xiao, Wenguang Tu, Shicheng Yan, Tingchao He, Xi Zhu, Yingfang Yao, Yong Zhou, Zhigang Zou
Summary: This study reveals the behavior of charge carriers in rutile TiO2 nanorod photoanodes using a novel spectroelectrochemistry technique, and demonstrates the impact of tuning the density of surface polaron states through electrochemical protonation on the photogenerated electrons in the electrode.
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
(2021)
Article
Materials Science, Multidisciplinary
Liang Li, Yong Yang, Boye Zhou, Yong Zhou, Zhigang Zou
Summary: A dimensional matched ultrathin BiVO4/Ti3C2Tx MXene 2D/2D heterosystem was developed through a simple electrostatic self-assembly process, which exhibited increased CO2 uptake capacity compared to bare BiVO4 nanosheets. Furthermore, the well-collaborated 2D/2D heterogeneous structure efficiently enhanced photoexcited charge transfer and separation, leading to a photocatalytic CH3OH production rate 4.1 times higher than pristine BiVO4.
Review
Chemistry, Multidisciplinary
Zhiwei Wang, Heng Zhu, Wenguang Tu, Xi Zhu, Yingfang Yao, Yong Zhou, Zhigang Zou
Summary: Photoelectrochemical hydrogen production from water splitting is a green technology that can convert solar energy into renewable hydrogen fuel, addressing environmental and energy issues. The construction of host/guest architecture in semiconductor photoanodes is an effective strategy to improve solar-to-fuel conversion efficiency by enhancing light-harvesting and charge collection and separation efficiency.
Article
Chemistry, Physical
Jiaqi Dong, Jianqiang Hu, Anyu Liu, Jiale He, Qingling Huang, Yanru Zeng, Wenjing Gao, Zhen Yang, Yongcai Zhang, Yong Zhou, Zhigang Zou
Summary: Direct Z-scheme MgIn2S4/Bi2WO6 hierarchical heterostructures were fabricated for efficient photocatalytic reduction of Cr(vi). The heterostructures showed significantly improved photocatalytic activity and light absorption, making them promising for environmental remediation applications.
CATALYSIS SCIENCE & TECHNOLOGY
(2021)
Article
Chemistry, Physical
Anyu Liu, Jianqiang Hu, Jiale He, Xinyue Huang, Na Hu, Yuqin Li, Qingling Huang, Shien Guo, Xin Liu, Zhen Yang, Yong Zhou, Zhigang Zou
Summary: The O-doped g-C3N4/In2S3 hierarchical heterostructures demonstrated a direct Z-scheme mechanism for enhanced photocatalytic activity in reducing Cr(vi) under visible light illumination. The efficient separation of photogenerated electrons and holes, as well as the enhanced responsiveness to visible light, contribute to the improved photocatalytic performance of the hybrids. The optimal OCN/IS hybrid with a mass ratio of 0.9 (OCN/IS-0.9) showed the highest Cr(vi) reduction efficiency with a reaction rate constant significantly higher than pure OCN and pristine IS photocatalysts.
CATALYSIS SCIENCE & TECHNOLOGY
(2021)
Article
Chemistry, Physical
Yintong Zhang, Feng Du, Ruyi Wang, Xintong Ling, Xiaoyong Wang, Qing Shen, Yujie Xiong, Tao Li, Yong Zhou, Zhigang Zou
Summary: A hybrid electrocatalyst composed of Au nanoparticles and oxygen vacancy-enriched niobium oxide nanobelts was prepared on niobium foil for N-2 fixation into NO3-. Electron transfer between Au nanoparticles and oxygen vacancies in Nb2O5-x nanobelts was found to adjust the electronic structures near the interface, suppressing the competitive OER activity and enhancing the NOR performance of the electrocatalyst.
JOURNAL OF MATERIALS CHEMISTRY A
(2021)
Article
Chemistry, Physical
Yiqing Wei, Huichao He, Chang Liu, Liuqing Yang, Xiaoyong Wang, Aidong Li, Yujie Xiong, Qing Shen, Yong Zhou, Zhigang Zou
Summary: A new type of α-Fe2O3/Ag/CdS ternary heterojunction film was constructed and investigated for solar water oxidation, achieving higher photocurrent density by enhancing charge separation and transfer efficiency as well as reducing electron-hole recombination through surface plasmon resonance effect.
CATALYSIS SCIENCE & TECHNOLOGY
(2021)
Article
Chemistry, Physical
Xintong Ling, Feng Du, Yintong Zhang, Yan Shen, Wa Gao, Bo Zhou, Zhiyuan Wang, Guoling Li, Tao Li, Qing Shen, Yujie Xiong, Xiaoyong Wang, Yong Zhou, Zhigang Zou
Summary: In this study, a Fe2Co-MIL-88B MOF on nickel foam was prepared through a solvothermal process, exhibiting superior OER activity due to the in situ formation of Fe0.67Co0.33OOH as the real active species during OER. The electron transfer between Fe and Co, positive coupling effect between Co and Fe, and the change of electronic structure caused by Fe metal ion substitution of Co were identified as key factors contributing to the significantly improved electrocatalytic performance.
JOURNAL OF MATERIALS CHEMISTRY A
(2021)
Article
Chemistry, Physical
Jie Lin, Jiale He, Jianqiang Hu, Jiaqi Dong, Anyu Liu, Yong Yang, Lanqin Tang, Liang Li, Yong Zhou, Zhigang Zou
Summary: The direct 2D/2D Z-scheme heterostructures of ZnIn2S4/Bi2MoO6 were constructed for photocatalytic Cr(VI) reduction, showing enhanced activity by effectively promoting spatial separation and migration of photoinduced carriers. The optimized ZnIn2S4/Bi2MoO6 photocatalyst exhibited close to 100% Cr(VI) reduction after 60 min of irradiation, with a reaction rate constant more than one order of magnitude higher than that of pure Bi2MoO6, contributing to high-efficiency photocatalytic materials for environmental pollution remediation applications.
CATALYSIS SCIENCE & TECHNOLOGY
(2021)