4.1 Article

Magnetic and Electronic Properties of RENiBi (RE = Pr, Sm, Gd-Tm, Lu) Compounds

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ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
卷 634, 期 12-13, 页码 2418-2422

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WILEY-V C H VERLAG GMBH
DOI: 10.1002/zaac.200800160

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Rare-earth compounds; semiconductors; magnetic properties

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  1. DfG [FE633/1-1]

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Resistivity and magnetic measurements were used to examine the ternary rare earth compounds RENiBi (RE = Pr, Sm, Gd-Tm, Lu). These compounds order antiferromagnetically with T-N below 16 K (RE = Pr, Sm, Gd-Tm) or are paramagnetic (LuNiBi). For some of these compounds a metal-insulator transition was found. The metal-insulator transition temperature depends strongly on the preparation conditions. Both the magnetic ground states and the resistance behavior are in good agreement with electronic band structure calculations.

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