Tribological behavior of graphite-containing nickel-based composite as function of temperature, load and counterface

Nickel-based graphite-containing composites were prepared by powder metallurgy method. Their mechanical properties at room temperature and friction and wear properties from room temperature to 600 degrees C were investigated by a pin-on-disk tribometer with alumina, silicon nitride and nickel-based alloy as counterfaces. The effects of graphite addition amount, temperature, load, sliding speed and counterface materials on the tribological properties were discussed. The micro-structure and worn surface morphologies were analyzed by scanning electron microscope (SEM) attached with energy dispersive spectroscopy (EDS). The results show that the composites are mainly consisted of nickel-based solid solution, free graphite and carbide formed during hot pressing. The friction and wear properties of composites are all improved by adding 6-12 wt.% graphite while the anti-bending and tensile strength as well as hardness decrease after adding graphite. The friction coefficients from room temperature to 600 degrees C decrease with the increase of load, sliding speed while the wear rates increase with the increasing temperature, sliding speed. The lower friction coefficients and wear rates are obtained when the composite rubs against nickel-based alloy containing molybdenum disulfide. Friction coefficients of graphite-containing composites from room temperature to 600 degrees C are about 0.4 while wear rates are in the magnitude of 10(-5) mm(3)/(N m). At high temperature, the graphite is not effective in lubrication due to the oxidation and the shield of 'glaze' layer formed by compacting back-transferred wear particles. EDS analysis of worn surface shows that the oxides of nickel and molybdenum play the main role of lubrication instead of graphite at the temperature above 400 degrees C. (C) 2008 Elsevier B.V. All rights reserved.