期刊
CHEMISTRYOPEN
卷 4, 期 3, 页码 212-223出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/open.201500018
关键词
chemoselectivity; continuous flow; diastereoselectivity; reactors; residence time
资金
- Hungarian Research Foundation (OTKA) [NK81371, PD103994]
- Tarsadalmi Megujulas Operativ Program (TAMOP) [4.2.2/B-10/1-2010-0012]
- Janos Bolyai scholarship from the Hungarian Academy of Sciences
- Postdoctoral Research Program of the Hungarian Academy of Sciences
As a sustainable alternative for conventional batch-based synthetic techniques, the concept of continuous-flow processing has emerged in the synthesis of fine chemicals. Systematic tuning of the residence time, a key parameter of continuous-reaction technology, can govern the outcome of a chemical reaction by determining the reaction rate and the conversion and by influencing the product selectivity. This review furnishes a brief insight into flow reactions in which high chemo- and/or stereoselectivity can be attained by strategic residence-time control and illustrates the importance of the residence time as a crucial parameter in sustainable method development. Such a fine reaction control cannot be performed in conventional batch reaction set-ups.
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