Article
Chemistry, Physical
Tatiana Latychevskaia, Colin Robert Woods, Yi Bo Wang, Matthew Holwill, Eric Prestat, Sara Mustafi, Sarah J. Haigh, Konstantin S. Novoselov
Summary: This study demonstrates the possibility of directly measuring scattering parameters through the intensity distribution of spots in CBED patterns. A method for recovering atomic scattering parameters from CBED patterns is proposed and validated through experiments and simulations.
Article
Chemistry, Physical
Ardavan Makvandi, Sandra Lobe, Michael Wolff, Martin Peterlechner, Christoph Gammer, Yaser Hamedi Jouybari, Sven Uhlenbruck, Gerhard Wilde
Summary: Although LiCoO2 electrode has high theoretical capacity, only half of it can be utilized in commercial cells due to chemical and structural instabilities at high charge cut-off voltages. Coating layers, especially Al-doped ZnO (Al:ZnO), are found to effectively mitigate the surface degradation and improve capacity retention. Analytical transmission electron microscopy (TEM) was used to study the degradation mechanisms and the suppression effects of the coating layer during electrochemical cycling.
JOURNAL OF POWER SOURCES
(2023)
Article
Chemistry, Multidisciplinary
Ardavan Makvandi, Michael Wolff, Sandra Lobe, Bastian Heidrich, Martin Peterlechner, Christoph Gammer, Sven Uhlenbruck, Martin Winter, Gerhard Wilde
Summary: In this study, the degradation mechanism of uncoated and Al:ZnO-coated NMC-111 electrodes under high charge cut-off voltages was systematically investigated. The results showed that the uncoated electrodes suffered from pitting corrosion, cation mixing, and an irreversible phase transformation, leading to capacity fading. However, the Al:ZnO coating layer mitigated these issues and improved the capacity retention and rate capability by protecting the electrode surface from direct electrolyte exposure.
ADVANCED MATERIALS INTERFACES
(2023)
Article
Materials Science, Multidisciplinary
Tae-Young Kim, Tae-Wook Na, Hyung-Seok Shim, Kyehwan Gil, Nong-Moon Hwang
Summary: The size of sub-boundary angles affects the selective abnormal grain growth of Goss-oriented grains, with smaller sub-boundary energies resulting in larger grains. Measurements of subboundary angles for different sizes of Goss grains confirmed that the sub-boundary angle is a determining parameter for the size of abnormally growing grains.
MATERIALS CHARACTERIZATION
(2022)
Article
Materials Science, Multidisciplinary
Alberto Binetti, Wei-Fan Hsu, Koen Schouteden, Jin Won Seo, Jean-Pierre Locquet, Maria Recaman Payo
Summary: Vanadium sesquioxide (V2O3) is a promising material for new-generation sensors or smart devices due to its strong correlation effects and tunable metal-insulator transitions. The successful growth of epitaxial thin films on silicon substrates has been achieved by adjusting the growth conditions, and extensive characterization has been carried out. Structural analysis reveals the impact of temperature on thin film microstructures, and the lattice mismatch between silicon and V2O3 induces the growth of the corundum PI phase. Additionally, small deviations from stoichiometry significantly affect the resistivity change upon cooling.
RESULTS IN PHYSICS
(2023)
Article
Physics, Applied
Masahiro Mori, Masashi Akabori, Masahiko Tomitori, Takashi Masuda
Summary: Researchers have successfully demonstrated the conversion of liquid silicon to solid silicon using liquid-phase electron beam-induced deposition, allowing for the direct deposition of semiconducting silicon. This technique has the potential to enable the production of high-resolution silicon nanostructures and access to previously inaccessible devices.
JAPANESE JOURNAL OF APPLIED PHYSICS
(2021)
Article
Engineering, Electrical & Electronic
J. von Borany, H-j Engelmann, K-h Heinig, E. Amat, G. Hlawacek, F. Kluepfel, R. Huebner, W. Moeller, M-l Pourteau, G. Rademaker, M. Rommel, L. Baier, P. Pichler, F. Perez-Murano, R. Tiron
Summary: This study presents the fabrication of vertically stacked Si/SiO2/Si nanopillars with embedded Si nanodots, which serve as key elements for a gate-all-around single-electron transistor. The process combines bottom-up and top-down technologies to satisfy the requirements of future 3D device architectures. The formation of single Si nanodots within a confined oxide volume is experimentally validated. The optimized conditions for nanopillar/nanodot formation and the influence of critical dimension variability on the transistor functionality are discussed.
SEMICONDUCTOR SCIENCE AND TECHNOLOGY
(2023)
Article
Nanoscience & Nanotechnology
G. De Luca, J. Spring, U. Bashir, M. Campanini, R. Totani, C. Dominguez, A. Zakharova, M. Dobeli, T. Greber, M. D. Rossell, C. Piamonteze, M. Gibert
Summary: The study shows that LNMO thin films maintain insulating behavior and a stable Curie temperature, regardless of the epitaxial strain conditions. This suggests that this material could be used in multi-layer device architectures that require a high-temperature ferromagnetic insulating state.
Article
Nanoscience & Nanotechnology
Aina Edgren, Erik Stroem, Ren Qiu, Lars Frisk, Farid Akhtar, Magnus Hoernqvist Colliander
Summary: Polycrystalline Mo(Si,Al)(2) with C40 crystal structure was deformed in compression at a high temperature. The study revealed characteristics such as maximum stress and strain rate, as well as the occurrence of dynamic recrystallization and low angle grain boundary formation.
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING
(2022)
Article
Chemistry, Multidisciplinary
Can Zou, Zixuan Zhao, Mingjun Xu, Xingfu Wang, Qing Liu, Kai Chen, Longfei He, Fangliang Gao, Shuti Li
Summary: To address the issue of minority carrier storage time in bipolar transistors, a hot electron transistor (HET) has been proposed. This device offers high working speed and the ability to perform complex logic functions with just one component. A mixed-dimensional HET composed of GaN/AlN microwires, graphene (Gr), and Si has been demonstrated, which achieves high speed hot electrons by injecting electrons between GaN/AlN into graphene through F-N tunneling mechanism, allowing for ballistic transport and collection through low-barrier Si. The device exhibits a record DC gain of 16.2, collection efficiency close to the limit of 99.9% based on GHET, emitter current density of 68.7 A/cm2, high on/off current ratio of approximately 107, and wide current saturation range, making it suitable for potential applications as a power amplifier.
Article
Physics, Applied
Yunhui Dong, Wei He, Wen Zhang, Mingli Dong
Summary: In this experiment, an equal-period plane diffraction grating fabricated through electron beam lithography line-by-line method was designed and applied to angle sensitivity testing. The diffraction wavelength remained basically unchanged when the spot moved horizontally by 50 mm. Adjusting the incident light angle from 15 degrees to 31 degrees resulted in a change in diffraction wavelength from 834.03 nm to 1589.80 nm, with an angular sensitivity of 47.508 nm/degrees and a linearity of 0.9998.
MODERN PHYSICS LETTERS B
(2021)
Article
Physics, Multidisciplinary
Rui Yu, Zhe Sheng, Wennan Hu, Yue Wang, Jianguo Dong, Haoran Sun, Zengguang Cheng, Zengxing Zhang
Summary: A field-effect WSe2/Si heterojunction diode based on ambipolar 2D WSe2 and silicon on insulator (SOI) are reported in this paper. The device exhibits p-n diode behavior with a rectifying ratio of about 300 and an ideality factor of 1.37. As a photodetector, it has optoelectronic properties with a response time of 0.13 ms, responsivity of 0.045 A/W, detectivity of 4.5x10(10) Jones, and external quantum efficiency (EQE) of 8.9%. The rectifying and optoelectronic properties of the heterojunction diode can be modulated by the gate electrical field due to the ambipolar behavior of the WSe2.
Article
Chemistry, Multidisciplinary
Zhexin Tang, Tongtong Shang, Han Xu, Ting Lin, Ang Gao, Weiguang Lin, Xinyan Li, Shiyu Wang, Botao Yu, Fanqi Meng, Qinghua Zhang, Xuefeng Wang, Dong Su, Qingbo Meng, Lijun Wu, Lin Gu, Ce-Wen Nan
Summary: The physical properties of materials are determined by the valence electron configurations, and different valence shells lead to different phenomena. In this study, we examined the valence electron density and orbital population of Sc2+ in the compound ScS using quantitative convergent-beam electron diffraction. Our results show that the 4s orbital is occupied by Sc2+, which is unexpected as it is usually the 3d orbital that is occupied in transition metal atoms. This finding reveals a unique electron configuration in a transition metal compound and suggests potential ways to modulate material properties by controlling electron orbitals.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Crystallography
Keisuke Arimoto, Taisuke Fujisawa, Daichi Namiuchi, Atsushi Onogawa, Yuichi Sano, Daisuke Izumi, Junji Yamanaka, Kosuke O. Hara, Kentarou Sawano, Kiyokazu Nakagawa
Summary: This paper discusses the dependence of hole mobility on channel direction and strained Si layer thickness in strained Si/relaxed SiGe/Si(110) heterostructures, revealing detailed transport properties of (110)-oriented pMOSFETs with significant anisotropy in hole mobility. The study highlights the [110] direction as preferable for hole mobility and the importance of having a sufficiently thin strained Si layer for high mobility, while considering the physical mechanisms of anisotropy and thickness dependence.
JOURNAL OF CRYSTAL GROWTH
(2021)
Article
Engineering, Electrical & Electronic
Raseong Kim, Ian A. Young
Summary: Comprehensive benchmarking analyses of Si and Ge n-and pMOSFETs at a relevant technology node reveal that strained Ge may significantly improve the efficiency of nMOS, while the improvement for relaxed Ge pMOS may be limited by tunneling leakage and the improvement by strained Ge pMOS may also be limited by increased source-to-drain tunneling. However, both Ge n-and pMOS offer additional performance benefits at higher temperatures, including increased maximum supply voltage for Ge n-and pMOS due to less increase in tunneling leakage with temperature and further improvement in efficiency for strained Ge pMOS with high temperatures. These results highlight the potential advantages of strain in Ge n-and pMOS and underscore the importance of considering operating temperature for accurate assessment of performance improvement.
IEEE TRANSACTIONS ON ELECTRON DEVICES
(2023)
Article
Physics, Applied
Furong Han, Xiaobing Chen, Jianlin Wang, Xudan Huang, Jine Zhang, Jinghua Song, Banggui Liu, Yuansha Chen, Xuedong Bai, Fengxia Hu, Baogen Shen, Jirong Sun
Summary: The research reports on the growth behavior of heterostructures formed on interfaces with symmetry mismatch, specifically focusing on the growth of La2/3Sr1/3MnO3/YBaCo2O5+delta (LSMO/YBCO) on SrTiO3. High-quality crystal structures of LSMO and YBCO were observed without any atomic rearrangement at the interface. Surprisingly, LSMO buffered by YBCO shows perpendicular magnetic anisotropy (PMA) with robust stability, even with a thin YBCO layer. This phenomenon is attributed to orbital reconstruction and the formation of a covalent bond between Mn and Co caged by different oxygen polyhedrons.
JOURNAL OF PHYSICS D-APPLIED PHYSICS
(2021)
Article
Nanoscience & Nanotechnology
Xiang-Bo Xiao, Bang-Gui Liu
Summary: Researchers have discovered three stable freestanding oxide 2D monolayers using first-principles method, which are wide-gap semiconductors with large out-of-plane dipoles. The optical properties of these monolayers have been investigated and compared with graphene and MoS2. These findings are believed to be useful in novel electronic and optoelectronic devices utilizing emerging phenomena in perovskite oxide heterostructures.
Article
Physics, Condensed Matter
Xiaobing Chen, Jine Zhang, Banggui Liu, Fengxia Hu, Baogen Shen, Jirong Sun
Summary: Heterointerfaces between infinite-layer oxide and perovskite oxide exhibit distinct interfacial effects, including the presence of a two-dimensional electron gas (2DEG) that exists in both interface layers. The metallicity of the new interface is robust even as the thickness of the SrCuO2 layer decreases. The conducting states in the interface layer follow the d(xy) form due to the absence of apical oxygen.
JOURNAL OF PHYSICS-CONDENSED MATTER
(2022)
Article
Chemistry, Physical
San-Dong Guo, Xiao-Shu Guo, Xiu-Xia Cai, Bang-Gui Liu
Summary: In this study, a model for valley polarization transition at different valley points produced by biaxial strain is proposed, illustrated with a Janus GdClF monolayer. It is found that the strained GdClF monolayer always maintains energy bandgap, strong FM coupling, and PMA within the considered strain range. Compressive strain favors -K valley polarization, while tensile strain favors K valley polarization, with potential applications in multifunctional valleytronic and piezoelectric devices.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2022)
Article
Materials Science, Multidisciplinary
San-Dong Guo, Wen-Qi Mu, Bang-Gui Liu
Summary: Based on first-principles calculations, it was found that the monolayer RuBr2 can exhibit valley-polarized quantum anomalous Hall insulator (VQAHI) under certain conditions, which holds potential for electronic device applications. The study emphasizes the importance of electronic correlation and perpendicular magnetic anisotropy in investigating ferrovalley materials.
Article
Nanoscience & Nanotechnology
Bo-Wen Yu, Bang-Gui Liu
Summary: The study demonstrates that a stronger ferromagnetic H ' phase can be formed from a VSe2 monolayer by applying uniaxial stress or strain, leading to potential applications in high-performance spintronic and optoelectronic devices.
Article
Chemistry, Physical
San-Dong Guo, Meng-Xia Wang, Yu-Ling Tao, Bang-Gui Liu
Summary: In this work, the Janus monolayer YBrI is demonstrated to be a dynamically, mechanically, and thermally stable piezoelectric ferromagnetic material. The electronic correlation effects and magnetic anisotropy properties of YBrI are investigated, revealing its distinct physical properties. The study also discovers both in-plane and out-of-plane piezoelectricity in YBrI. The findings of these distinctive properties could pave the way for designing multifunctional spintronic devices and constructing 2D materials.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2022)
Article
Physics, Multidisciplinary
San-Dong Guo, Yu-Ling Tao, Wen-Qi Mu, Bang-Gui Liu
Summary: This study investigates the impact of spin-orbit coupling combined with electronic correlation on the physical properties of monolayer OsBr2. It is found that OsBr2 undergoes threefold topological phase transition with increasing correlation strength and can exhibit valley polarized quantum anomalous Hall insulator to half-valley-metal to ferrovalley insulator transitions. The topological phase transitions are associated with Berry curvature and band inversion between specific orbital states. The piezoelectric properties of OsBr2 are confined along the in-plane direction, and the valley polarization can be manipulated by reversing the magnetization.
FRONTIERS OF PHYSICS
(2023)
Article
Chemistry, Multidisciplinary
Wenxiao Shi, Jine Zhang, Xiaobing Chen, Qinghua Zhang, Xiaozhi Zhan, Zhe Li, Jie Zheng, Mengqin Wang, Furong Han, Hui Zhang, Lin Gu, Tao Zhu, Banggui Liu, Yunzhong Chen, Fengxia Hu, Baogen Shen, Yuansha Chen, Jirong Sun
Summary: By modifying the entangled multi-degrees of freedom of transition-metal oxides, the symmetry-mismatch-driven interfacial phase transition from paramagnetic to ferromagnetic state is achieved in this work. The interfacial layer of CaRuO3, with approximately 3 unit cells in thickness, shows robust ferromagnetic order with a high Curie temperature of approximately 120 K and a large saturation magnetization of approximately 0.7 mu(B) per formula unit. Density functional theory calculations reveal that the reduced tilting/rotation of RuO6 octahedra favors an itinerant ferromagnetic ground state. This study demonstrates an effective approach to tune phases by coupled octahedral rotations and offers new opportunities for the exploration of emergent materials with desired functionalities.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Zihao Huang, Guoyu Xian, Xiangbo Xiao, Xianghe Han, Guojian Qian, Chengmin Shen, Haitao Yang, Hui Chen, Banggui Liu, Ziqiang Wang, Hong-Jun Gao
Summary: Landau quantization in a strained type-II Dirac semimetal NiTe2 is studied using spectroscopic-imaging scanning tunneling microscopy. Single-sequence Landau levels originating from the quantization of topological surface state (TSS) are observed on uniform-height surfaces at a magnetic field. Multiple sequence of Landau levels appear in strained surface regions where the rotation symmetry is broken. First-principles calculations reveal that the multiple Landau levels are a result of the lifting of valley degeneracy of TSS by in-plane uniaxial or shear strains. This finding provides a pathway to tune the degrees of freedom and quantum numbers of TMDs for practical applications.
Article
Materials Science, Multidisciplinary
Xiaobing Chen, Jine Zhang, Banggui Liu, Fengxia Hu, Baogen Shen, Jirong Sun
Summary: We report a theoretical investigation on the effects of interface reconstruction on magnetic anisotropy (MA) and Dzyaloshinskii-Moriya interaction (DMI) for nonisostructural heterostructures. We found that the atomic, charge, spin, and orbital reconstructions at the interface allowed for a great tuning of the magnetic anisotropy oscillation behavior. We also observed a strong and tunable DMI, with the minimal value obtained at a specific interface.
Article
Materials Science, Multidisciplinary
San-Dong Guo, Yu-Tong Zhu, Jia-Lin Xin, Bang-Gui Liu
Summary: Through first-principles calculations, it has been found that stable monolayer Fe2Br2 possesses high Chern number and exhibits characteristics of a quantum anomalous Hall insulator. The out-of-plane magnetic anisotropy is crucial for the quantum anomalous Hall state and is robust against biaxial strain. These findings open new possibilities for designing high-temperature topological quantum devices.
JOURNAL OF MATERIALS CHEMISTRY C
(2022)
Article
Materials Science, Multidisciplinary
San-Dong Guo, Jing-Xin Zhu, Meng-Yuan Yin, Bang-Gui Liu
Summary: Electronic correlation and magnetic anisotropy play a crucial role in determining the electronic properties of materials. The study shows that increasing electron correlation effects can induce phase transitions, and magnetic anisotropy is strongly dependent on the U value. Different orbital distributions and magnetocrystalline directions also affect the material properties.
Article
Materials Science, Multidisciplinary
San-Dong Guo, Jing-Xin Zhu, Wen-Qi Mu, Bang-Gui Liu
Summary: This study introduces monolayer GdCl2 as a potential material for valleytronic applications, with strong FM coupling and a valley splitting of 42.3 meV. The research also discusses the possible way to achieve the anomalous valley Hall effect in monolayer GdCl2 using the piezoelectric effect.
Article
Chemistry, Physical
San-Dong Guo, Wen-Qi Mu, Xiang-Bo Xiao, Bang-Gui Liu
Summary: The monolayer FeI1-xBrx (x = 0.25 and 0.75) are proven to be stable and excellent room-temperature PQAHIs with high Curie temperatures, sizable gaps and high Chern number. The different crystal phases have significant effects on the out-of-plane piezoelectric response, with the beta phase having a higher piezoelectric strain coefficient.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2021)
Article
Microscopy
C. Gao, C. Hofer, T. J. Pennycook
Summary: Ptychography provides high dose efficiency images that can reveal light elements next to heavy atoms. However, contrast reversals can occur when the projected potential becomes strong. Recent research has shown that these reversals can be counteracted by adapting the focus. This study explains why the best contrast is often found with the probe focused to the middle of the sample and highlights the importance of convergence angle in thin samples to remove contrast reversals.
Article
Microscopy
J. Lindner, U. Ross, T. Meyer, V. Boureau, M. Seibt, Ch. Jooss
Summary: Phase-shifting electron holography is an excellent method with high phase sensitivity to reveal electron wave phase information. An advanced drift correction scheme is proposed in this study, which exploits the interface of the TEM specimen and the vacuum area in the hologram. This method allows for obtaining reliable phase information.
Article
Microscopy
Ali Jaberi, Nicolas Brodusch, Jun Song, Raynald Gauvin
Summary: This study investigates knock-on damage in lithium-ion batteries (LIBs) by computing threshold displacement energies (TDEs) and performing Monte Carlo simulation. The results indicate that Li is most sensitive to knock-on damage at moderate electron energies, and TDE is the principal parameter for assessing Li sensitivity to knock-on damage across similar structures.
Article
Microscopy
Alexander Schroeder, Christopher Rathje, Leon van Velzen, Maurits Kelder, Sascha Schaefer
Summary: This study utilizes novel event-based electron detector platforms to extend the temporal resolution of electron microscopy. By training a neural network to predict electron arrival time, the researchers were able to improve the timing accuracy and achieve a promising solution for enhancing electron timing precision in various electron microscopy applications.
Article
Microscopy
Avi Auslender, Nivedita Pandey, Amit Kohn, Oswaldo Dieguez
Summary: This article describes a faster implementation based on DFT for computing the mean inner potential of crystals, providing quantum-mechanical calculations beyond the independent-atom approximation. The study also reveals the dependence of the mean inner potential on sample boundary conditions, mass density, and magnetic susceptibility, highlighting its correlation with various material properties.
Article
Microscopy
Zhidong Yang, Dawei Zang, Hongjia Li, Zhao Zhang, Fa Zhang, Renmin Han
Summary: In this work, we propose a self-supervised deep learning model for cryo-ET volumetric image denoising based on noise modeling and sparsity guidance. Experimental results demonstrate that our method can achieve reliable denoising by training on single noisy volume and outperform existing methods.
Article
Microscopy
J. Kuttruff, J. Holder, Y. Meng, P. Baum
Summary: In this study, a robust clustering algorithm is proposed that can find clusters in a continuous stream of raw data in real time. This algorithm converts pixel hits measured by hybrid pixel detectors to real single-electron events. By continuously comparing with previous hits, the algorithm efficiently identifies the merging of new and old events.
Article
Microscopy
D. G. Senturk, C. P. Yu, A. De Backer, S. Van Aert
Summary: This article presents a statistics-based method for accurately counting the number of atoms in nanostructures, especially for images acquired with low electron doses and multiple element structures.
Article
Microscopy
Mauricio J. Prieto, Lucas de Souza Caldas, Liviu C. Tanase, Thomas Schmidt, Oscar Rodriguez de la Fuente
Summary: This study presents a synchrotron-based investigation of the synthesis process of a magnetite/hematite bilayer. Ion bombardment gradually transforms hematite into magnetite, and the growth of magnetite leads to the formation of stable boundaries. These findings are significant for understanding novel oxide heterostructures.
Article
Microscopy
Emre Yoruk, Holger Klein, Stephanie Kodjikian
Summary: Beam sensitive nanomaterials pose challenges for crystallographic structure determination. A dose symmetric electron diffraction tomography (DS-EDT) method is developed to reduce beam damage and obtain complete data sets by merging individual datasets from multiple crystals.
Article
Microscopy
A. Pofelski, Y. Zhu, G. A. Botton
Summary: The precision and sensitivity of the GPA method for strain characterization is a widely discussed topic. This study introduces the concept of phase noise and analyzes the parameter of sampling to improve the precision of GPA. Experimental and theoretical results demonstrate that using a larger pixel spacing in STEM can enhance the precision and sensitivity of the GPA method.
Article
Microscopy
Sangjun Kang, Di Wang, Christian Kuebel, Xiaoke Mu
Summary: Transmission electron microscopy is a valuable tool for assessing strain fields within materials. However, using thin specimens in TEM analysis can affect atomic configuration and deformation structure.