期刊
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
卷 4, 期 1, 页码 350-362出版社
AMER CHEMICAL SOC
DOI: 10.1021/acssuschemeng.5b01335
关键词
Poly(butylene succinate); Isosorbide; 2,3-O-Isopropylidene-L-threitol; Thermal stability; Crystallization; Mechanical property; Oxygen barrier property
资金
- National Science Foundation of China [51273123, 51421061, J1103315]
- Research Fund for the Doctoral Program of Ministry of Education of China [20120181110049]
- Program for Changjiang Scholars and Innovative Research Teams in University of China [IRT 1026]
In order to improve the mechanical and oxygen barrier properties of poly(butylene succinate) (PBS), two series of sugar-containing PBS copolyesters with different molecular stiffness were synthesized and comparatively investigated, in which a cyclic alditol, isosorbide (Is) or 2,3-O-isopropylidene-L-threitol (ITh) was, respectively, used as a comonomer. Both cyclic alditols were easily available from biomass feedstock, such that Is is a bicyclic compound derived from D-glucose, and ITh is a monocyclic acetalized compound coming from naturally occurring L-tartaric acid. All these copolyesters containing up to 30 mol % of sugar-based units had satisfactory number-average molecular weights in the 16 000-83 000 g mol(-1) range, and presented a random microstructure together with excellent thermal stability. The sugar-containing copolyesters were all semicrystalline and still possessed the monoclinic crystal structure of PBS. The incorporation of either Is or ITh units with rigid cyclic structure into PBS chain decreased the crystallinity and crystallization rate of PBS, while it enhanced its glass transition temperature. In addition, the partial replacement of 1,4-butanediol by sugar-based units endowed PBS with steadily enhanced hydrophilicity. Depending on the type and content of sugar units, the copolyesters show different oxygen barriers and mechanical properties. It was found that copolyester with bicyclic Is sugar units exhibited a better oxygen barrier and mechanical property than that with monocyclic ITh units.
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