期刊
TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA
卷 22, 期 -, 页码 S153-S156出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/S1003-6326(12)61701-4
关键词
LiFePO4; multiple-ion doping; Fe-site doping; solid state reaction; electrochemical performance
资金
- National Natural Science Foundation of China [51002128]
- National Science Foundation for Post-Doctor of China [2012M511737]
LiFePO4 co-doped with Mg2+ and Co4+ ions was synthesized by a solid state reaction method. The structure and electrochemical properties of the prepared LiFe0.99Mg0.005Co0.005PO4 were investigated by X-ray diffraction (XRD), galvanostatic charge-discharge experiment and cyclic voltammograms (CV). Specific discharge capacity of LiFePO4 co-doped with Mg and Co ions reach 147.2 mA.h/g at 0.1C and 133.3 mA.h/g at 1C. The results of CV show that the reversibility of lithium extraction/insertion in LiFePO4 can be promoted by (Mg2+, Co4+) multiple-ion doping.
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