期刊
TOPICS IN CATALYSIS
卷 57, 期 10-13, 页码 1015-1025出版社
SPRINGER/PLENUM PUBLISHERS
DOI: 10.1007/s11244-014-0265-9
关键词
Copper; Platinum; Alloy; Dimethyl oxalate; Hydrogenation; Ethylene glycol
资金
- National Basic Research Program of China [2011CBA00508]
- Natural Science Foundation of China [21173175, 20923004]
- Research Fund for the Doctoral Program of Higher Education [20110121130002]
- Program for Changjiang Scholars and Innovative Research Team in University [IRT1036]
Cu/SBA-15 catalysts containing a small amount of Pt (Cu-Pt/SBA-15) were prepared by sequential adsorption-reduction method and examined for chemoselective hydrogenation of dimethyl oxalate(DMO) to ethylene glycol (EG). The Cu-Pt/SBA-15 catalyst with an optimal Cu/Pt atomic ratio of 10 showed a DMO conversion close to 100 % with a 98 % selectivity to EG at a temperature as low as 463 K. The results showed that the best Cu-Pt/SBA-15 enhanced the space time yield of EG by about 1.47 times compared with Cu/SBA-15. The introduction of Pt with stronger ability for H-2 adsorption and activation substantially enhanced the reducibility of the Cu2+ species and further promoted the chemisorption capacity of H-2. After reduction, a portion of Cu was alloyed with Pt, which was beneficial for the generation and stabilization of a balanced Cu+/Cu-0 ratio during the hydrogenation process.
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