期刊
TOPICS IN CATALYSIS
卷 57, 期 10-13, 页码 935-939出版社
SPRINGER/PLENUM PUBLISHERS
DOI: 10.1007/s11244-014-0254-z
关键词
Calcium chloride; Flow reaction; C-C bond formation; 1,4-Addition reaction; Asymmetric catalysis
资金
- Japan Society for the Promotion of Science (JSPS)
- Japan Science and Technology Agency (JST)
Pybox-CaCl2 was found to be an efficient chiral catalyst for asymmetric 1,4-addition reactions of 1,3-dicarbonyl compounds with nitroalkenes, affording gamma-nitro carbonyl compounds in high yields with high enantioselectivities. The reactions proceeded smoothly even in air, and were successfully applied to a continuous flow system.
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