期刊
TOPICS IN CATALYSIS
卷 56, 期 9-10, 页码 679-687出版社
SPRINGER/PLENUM PUBLISHERS
DOI: 10.1007/s11244-013-0025-2
关键词
Dichloromethane oxidation; DCM; Chlorinated volatile organic compounds; CVOC; Metal oxide catalysts
资金
- PHC Volubilis
Three different transition metals (V, Mn and Cu) supported on TiO2, MgO and CeO2, were investigated for their performances in dichloromethane oxidation (500 ppm, 704,867 h(-1)) in moist conditions as a model reaction for the destruction of chlorinated volatile organic compounds. The catalysts were prepared by sol-gel method followed by wet impregnation of V, Mn or Cu precursors. The activities were evaluated in the temperature range from 100 to 500 A degrees C with 5 A degrees C min(-1) temperature rise. The orders of activity and selectivity to HCl of the catalysts is CuTi > VMg > CuCe > CuMg. A correlation between acidic properties of support and performances was observed as the activity of copper catalysts followed the acidity order of supports.
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