期刊
TOPICS IN CATALYSIS
卷 54, 期 19-20, 页码 1357-1367出版社
SPRINGER/PLENUM PUBLISHERS
DOI: 10.1007/s11244-011-9762-2
关键词
Chirality; Self-assembly; Dipole moment; Scanning tunneling microscopy; Thioether
资金
- National Science Foundation
- Department of Energy, Research Corporation
- Beckman Foundation
- National Science Foundation [DMR-0906727]
- Robert a Welch Foundation [E-1320]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0844343] Funding Source: National Science Foundation
- Direct For Mathematical & Physical Scien
- Division Of Materials Research [0906727] Funding Source: National Science Foundation
There is a growing interest in chirality at surfaces from both a fundamental and an enantioselective reactions/separations viewpoint. We report on the homo-chiral self-assembly of asymmetric thioethers that become chiral upon binding to a surface. We focus on the adsorption of butyl methyl sulfide and a fluorinated analogue on Au(111) surfaces.
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