期刊
TOPICS IN CATALYSIS
卷 53, 期 15-18, 页码 1096-1103出版社
SPRINGER/PLENUM PUBLISHERS
DOI: 10.1007/s11244-010-9540-6
关键词
Catalysis; Catalyst modification; Selective hydrogenation; Ionic liquid; Multiphase reactions; Supported ionic liquid catalyst (SILCA)
资金
- Academy of Finland [124640, 209391, 211463]
- Academy of Finland (AKA) [124640, 211463, 124640, 209391, 209391, 211463] Funding Source: Academy of Finland (AKA)
Supported Ionic Liquid Catalysts (SILCA) designed by immobilization of catalytic species residing in an ionic liquid layer, which in turn was immobilized on a solid support, were applied on the selective hydrogenation of citral in a batch reactor and in a continuous reactor. Different ionic liquids with and without addition of acid modificators were studied in terms of the catalyst activity and product selectivity. Consequently, mechanistic kinetic models describing the differences in the activity and selectivity of the catalysts consisting different ionic liquids, were developed.
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