期刊
TOPICS IN CATALYSIS
卷 52, 期 1-2, 页码 27-34出版社
SPRINGER/PLENUM PUBLISHERS
DOI: 10.1007/s11244-008-9135-7
关键词
Methane combustion; Zeolite-supported Pd catalysts; Support microstructure
Methane combustion was conducted over Pd catalysts supported on medium (ZSM-5, ferrierite, TNU-9, TNU-10) and large (USY, mordenite, beta) pore zeolites. Among the catalysts studied here, Pd/H-TNU-10 exhibited the highest combustion activity, together with excellent durability in the presence of water vapor. A combination of TEM and Pd K-edge XAFS measurements reveals the formation of highly dispersed PdO particles within the TNU-10 pores. This is also the case of Pd/H-ferrierite, while frequently there are large particles (60-100 A...) on its outer surface. In contrast, most of PdO on zeolites other than these two medium pore materials were found to exist as aggregated particles (> 50 A...) on their outer crystallite surface. It appears that zeolite structures with intersecting 10- and 8-ring pores may be better supports for stabilizing nanometric PdO particles than those with the uniform 10-ring size or with the 12-ring pore system.
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