期刊
TETRAHEDRON-ASYMMETRY
卷 23, 期 13, 页码 938-944出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetasy.2012.06.020
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A double catalyst system (protease + base) was applied to the dynamic kinetic resolution (DKR) of isomeric 1- and 2-alpha-naphthyl-glycines and -alanines exploiting the in situ racemization of their thioesters. Due to the different C-acidity of the two sets of compounds, different experimental conditions have been devised to perform the simultaneous resolution/racemization process. In all cases, the racemic N-Boc-thioesters were converted into the aminoacids with an L-configuration almost quantitatively and with complete enantioselectivity. (C) 2012 Elsevier Ltd. All rights reserved.
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