期刊
TETRAHEDRON-ASYMMETRY
卷 21, 期 9-10, 页码 1166-1168出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetasy.2010.04.016
关键词
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资金
- JSPS
- Promotion of Basic Research Activities for Innovative Biosciences (PROBRAIN)
- JST/JICA, SATREPS
- [20580111]
A synthetic intermediate of an optically active strigolactone analogue was prepared in two ways: enzymatic resolution and asymmetric hydroxylation. The 4-hydroxy tricyclic lactone 4 was enzymatically resolved to give the corresponding enantiomers in an enantiomerically pure state, while the tricyclic lactone 5 was hydroxylated asymmetrically at the 4-position by the action of cytochrome P450 monooxygenase. (C) 2010 Elsevier Ltd. All rights reserved.
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