期刊
TETRAHEDRON LETTERS
卷 55, 期 18, 页码 2965-2968出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2014.03.108
关键词
Absolute configuration; Schizandrin; VCD; ECD
资金
- Hebei University
- National Natural Science Foundation of China (NSFC) [21202033]
- Natural Science Foundation of Hebei Province [C2012201047]
- Foundation of Hebei University [179]
Bioactive natural product (+)-schizandrin was assigned as (7S,8S) using NMR. Recently, we obtained (+)schizandrin from TCM Schisandra sphenanthera Rehd. et Wils. Its planar structure was well established using NMR and HR-MS including the reported references. Its absolute configuration is assigned using vibrational circular dichroism (VCD). By careful VCD investigation of (75,8S) and (75,8R) using B3LYP/6-311+G(d) methods, absolute configuration of (+)-schizandrin is assigned as (7S,8R). Electronic circular dichroism (ECD) was used for the discussion too and it gave the same conclusion. (C) 2014 Elsevier Ltd. All rights reserved.
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