期刊
TETRAHEDRON LETTERS
卷 55, 期 14, 页码 2230-2232出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2014.02.076
关键词
Allylic hydroperoxide; Oxidative cleavage; Hypervalent iodine; Ozonolysis; Alkenes
资金
- Scientific and Technological Research Council of Turkey (TUBITAK) [TBAG-107T390]
Unsaturated C=C double bonds with a phenyl substituent can be cleaved with iodylbenzene and iodosylbenzene to give carbonyl compounds. It is believed that the reactions occur via a radical pathway. The allylic oxidation of cyclic alkenes lacking a phenyl substituent was achieved in acetonitrile/water mixture (3:1) also using iodylbenzene and iodosylbenzene. (C) 2014 Elsevier Ltd. All rights reserved.
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