期刊
TETRAHEDRON LETTERS
卷 54, 期 19, 页码 2366-2368出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2013.02.083
关键词
Inverse electron-demand Diel-Alder; Methyl coumalate; Vinyl ether; Ketal; Orthoester; Functionalized aromatics
资金
- NSF Engineering Center for Biorenewable Chemicals [EEC-0813570]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1040098] Funding Source: National Science Foundation
An inverse electron-demand Diels-Alder reaction between methyl coumalate and electron-rich dienophiles produces substituted benzoates. A high-yielding, single-pot procedure transforms readily accessible vinyl ether, ketal, or orthoester dienophiles into functionalized aromatic systems in a versatile route. (C) 2013 Elsevier Ltd. All rights reserved.
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