期刊
TETRAHEDRON LETTERS
卷 54, 期 47, 页码 6337-6340出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2013.09.048
关键词
Iron catalysis; Carbonylation; Arylation; Oxindoles
资金
- National Science Foundation of China [21072223, 21272267]
- State Key Laboratory of Heavy Oil Processing [2012-1-06]
- Fundamental Research Funds for the Central Universities
- Research Funds of Renmin University of China [10XNL017]
An efficient method for oxindole synthesis is established by iron-catalyzed carbonylation-arylation of N-arylacrylamides with aldehydes. 3-Functionalized oxindoles are synthesized smoothly using FeCl3 as catalyst and TBHP as oxidant. The obtained oxindoles can be used for further transformations to give diverse indole alkaloid structure motifs. (C) 2013 Elsevier Ltd. All rights reserved.
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