期刊
TETRAHEDRON LETTERS
卷 54, 期 51, 页码 7004-7008出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2013.10.043
关键词
Bromolactonization reaction; Cinchona alkaloid; Asymmetric organocatalysis; Carboxylic acids; Additive effects
资金
- GlaxoSmithKline
- EPSRC [EP/E058272/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/E058272/1] Funding Source: researchfish
Catalytic (DHQD)(2)PHAL as modified by added benzoic acid, is an off-the-shelf catalyst-additive combination for effecting catalytic asymmetric bromolactonization reactions. This combination delivers bromolactones with asymmetric induction at a comparable level to bespoke catalysts previously optimized for particular substrate classes. (C) 2013 Elsevier Ltd. All rights reserved.
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