期刊
TETRAHEDRON LETTERS
卷 54, 期 28, 页码 3609-3612出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2013.04.087
关键词
Perfluoro and semifluorinated polymers; Perfluorocycloalkenes; Addition elimination reaction; Polycondensation
资金
- Intel Corporation [4606175]
- Welch Foundation [AT-0041]
- NSF-IUCRC [IIP-1035024]
- University of Texas at Dallas
A unique class of perfluorocycloalkenyl (PFCA) aryl ether monomers was synthesized from commercially available perfluorocycloalkenes (PFCAs) and bisphenols in good yields. This facile one pot reaction of perfluorocycloalkenes, namely, octafluorocyclopentene (OFCP), and decafluorocyclohexene (DFCH), with bisphenols occurs at room temperature via an addition-elimination reaction in the presence of a base. The synthesis of PFCA monomers and their condensation with bisphenols lead to perfluorocycloalkenyl (PFCA) aryl ether homopolymers and copolymers with random and/or alternating polymer architectures. Published by Elsevier Ltd.
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