期刊
TETRAHEDRON LETTERS
卷 54, 期 48, 页码 6479-6484出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2013.09.086
关键词
Al3+-exchanged on K10 clay; Imidazopyridine; Heterogeneous catalysis; Solid acids; Heterocycles
资金
- Department of Science and Technology, New Delhi, India
- University Grants Commission, New Delhi
A series of imidazopyridine derivatives have been synthesized efficiently via intramolecular cyclization in excellent yields using Al3+-exchanged on K10 montmorillonite clay (Al3+-K10 clay) as a reusable heterogeneous catalyst. To the best of our knowledge, this is the first report to utilize Al3+-K10 as a catalyst for imidazopyridine synthesis. Many functional groups are tolerated during the synthesis of targeted compounds. The catalyst is reused at least five times with a slight decrease in the yield. This catalyst is environmentally benign, cost-effective, and also provides other advantages such as nontoxicity, operational/experimental simplicity, and mild reaction conditions. (C) 2013 Elsevier Ltd. All rights reserved.
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