Review
Chemistry, Multidisciplinary
Jian-Gang Yu, Li-Ying Sun, Chong Wang, Yang Li, Ying-Feng Han
Summary: The coordination-driven self-assembly with TPE units has attracted much attention for applications in chemical sensors, cell imaging agents, light-harvesting systems, etc., thanks to the potential of aggregation-induced emission (AIE) phenomena. Recent advances have been made in the design and application of TPE-based metallacycles, metallacages, metal-organic frameworks (MOFs) and coordination polymers (CPs), leading to improved stabilities and enhanced chemical responses exhibited by the products.
CHEMISTRY-A EUROPEAN JOURNAL
(2021)
Article
Chemistry, Applied
Ya Yin, Hao Hu, Zhao Chen, Hongliang Liu, Congbin Fan, Shouzhi Pu
Summary: Four newly synthesized fluorescent dyes were reported, showing aggregation-induced emission effects and varying fluorescence colors. Interestingly, two of them could be switched in the solid state by mechanical or solvent actions, while the other two exhibited different fluorescence responses.
Article
Chemistry, Physical
Xiaoyi Zhang, Shengjie Jiang, Guoliang Lin, Hongyu Guo, Fafu Yang
Summary: In this study, two new tetraphenylethylene-rufigallol-tetraphenylethylene triads were synthesized with good fluorescence properties and studied for their liquid crystalline behaviors. The compound with dodecyl chains demonstrated lower phase transition temperatures and a wider mesophase temperature range compared to the other compound. These findings suggest that symmetrical trimers are an effective approach for constructing novel fluorescence columnar liquid crystals.
JOURNAL OF MOLECULAR STRUCTURE
(2022)
Article
Chemistry, Physical
Xiaoyi Zhang, Guoliang Lin, Hongyu Guo, Fafu Yang
Summary: This study reported two novel liquid crystals with good fluorescence in aggregated states, synthesized by a simple procedure. The columnar liquid crystalline behaviors and AIE fluorescence properties of the compounds were confirmed, showing that the properties can be tuned by the lengths of the terminal alkyl chains.
JOURNAL OF MOLECULAR STRUCTURE
(2022)
Article
Chemistry, Multidisciplinary
Jean Rouillon, Cyrille Monnereau, Chantal Andraud
Summary: The study experimentally evaluated the quantum efficiencies of photoisomerization and photocyclization in tetraphenylethylene molecules, demonstrating that photoisomerization is the dominant photophysical pathway in solution, responsible for nearly all nonradiative decay of the molecule's excited state in degassed solution.
CHEMISTRY-A EUROPEAN JOURNAL
(2021)
Article
Chemistry, Applied
Nagendra Kalva, Chinh Hoang Tran, Min Woong Lee, Rimesh Augustine, Soo Jeong Lee, Il Kim
Summary: This study developed a facile synthesis method for AIE-active HPGs and designed a solid-state sensor for detecting nitroaromatic explosives. The resulting AIE-active HPGs showed excellent AIE characteristics and high sensitivity towards nitro compounds by conjugating tetraphenylethylene moieties onto the periphery of the HPGs.
Article
Chemistry, Analytical
Cheng Zhang, Xihao Pan, Siyao Cheng, Aming Xie, Wei Dong
Summary: With the increasingly severe international security situation, the demand for rapid and effective detection of explosives is growing. Research has found that by synthesizing two novel probes, it is possible to specifically detect the explosive FOX-7, providing the possibility for practical applications.
ANALYTICA CHIMICA ACTA
(2021)
Article
Chemistry, Multidisciplinary
Hanchen Shen, Wenjie Wu, Shunjie Liu, Jing Zhang, Jacky W. Y. Lam, Ben Zhong Tang
Summary: In this study, tetraphenylethylene-based trithiocarbonate polymers with high molecular weights were successfully synthesized, exhibiting non-emissive properties but strong emission under UV irradiation. This unique feature provides them with potential applications in photopatterning, anti-counterfeit labels, and UV detection.
CHINESE JOURNAL OF CHEMISTRY
(2021)
Article
Nanoscience & Nanotechnology
Xiaoning Guo, Tong Song, Dong Chen, Jinchang Zhu, Zhenlin Li, Qing Xia, Li Wang, Wantai Yang
Summary: Researchers synthesized and utilized tetraphenylethylene (TPE)-containing monomers to prepare TPE-appended maleic anhydride terpolymers. These terpolymers exhibited fluorescence changes in response to pH, ionic strength, Ca2+, and bovine serum albumin, thanks to the synergistic interaction of the TPE moiety and the terpolymer conformation change. The insights gained from this study are important for developing efficient and versatile stimuli-responsive AIE-active polymer platforms for chemo-sensing and bioimaging.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Chemistry, Multidisciplinary
Anna Brzechwa-Chodzynska, Grzegorz Markiewicz, Piotr Cecot, Jack Harrowfield, Artur R. Stefankiewicz
Summary: In this study, we describe the self-assembly of a tetraphenylethylene (TPE) derivative with amino acid substitution into a hydrogen-bonded dimeric capsule. Depending on the conditions, the TPE derivative exhibits bluish photoluminescence with QYs up to 24% due to the AIE effect and excimer formation.
CHEMICAL COMMUNICATIONS
(2023)
Article
Polymer Science
Haoying Wang, Fangyu Wang, Pengpeng Deng, Jinping Zhou
Summary: Functional polymer based on renewable material MC was modified with TPE to form a fluorescent derivative with thermoresponsive and biocompatible properties, suitable for bioimaging applications.
MACROMOLECULAR RAPID COMMUNICATIONS
(2021)
Article
Chemistry, Multidisciplinary
Xiang Li, Qin Zhou, Miao Zhu, Wei Chen, Beibei Wang, Ye Sha, Hong Yan
Summary: A novel star-shaped molecule based on TPE-o-carborane with a triphenylamine core has been synthesized, showing an improved luminescent quantum yield of 62% in the solid state.
NEW JOURNAL OF CHEMISTRY
(2021)
Article
Chemistry, Multidisciplinary
Lian Zhou, Wei Meng, Lin Sun, Lin Du, Xiaopeng Xuan, Jun Zhang
Summary: A study introduced an organic functional group to distinguish the four phenyl rings of tetraphenylethylene, and determined the in situ temperature-dependent crystal structures to show conformational changes of tert-butyl (3-(1,2,2-triphenylvinyl)phenyl)carbamate (BTPC). The isotropic displacement parameters of each phenyl further confirmed the inequivalent vibrations of the molecule due to the crystal's anisotropy.
Article
Chemistry, Multidisciplinary
Chaoqun Mu, Zeyuan Zhang, Yali Hou, Haifei Liu, Lingzhi Ma, Xiaopeng Li, Sanliang Ling, Gang He, Mingming Zhang
Summary: By using multi-component emissive metallacages as solid-state fluorescent materials, high quantum yield emission performance was achieved by restricting molecular motions and suppressing non-radiative decay. One of the metallacages exhibited very high fluorescence quantum yield in the solid state and was successfully applied as a coating for white-light emission in a blue LED bulb.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Chemistry, Analytical
Guanjun Pan, Tingting Xia, Yi He
Summary: The newly synthesized sensor 1 can dissolve in water and exhibit significant fluorescence enhancement response towards PO43- with high selectivity and sensitivity.
Article
Chemistry, Physical
Kuheli Mandal, Debabrata Jana, Binay K. Ghorai, Nikhil R. Janast
JOURNAL OF PHYSICAL CHEMISTRY C
(2016)
Article
Biochemistry & Molecular Biology
Debashis Patra, Subhabrata Paul, Nayim Sepay, Rita Kundu, Tapas Ghosh
JOURNAL OF BIOMOLECULAR STRUCTURE & DYNAMICS
(2018)
Article
Chemistry, Multidisciplinary
Pritam Biswas, Jaydip Ghosh, Tapas Sarkar, Debabrata Jana, Chandrakanta Bandyopadhyay
NEW JOURNAL OF CHEMISTRY
(2017)
Article
Nanoscience & Nanotechnology
Sandip Biswas, Debabrata Jana, Gundam Sandeep Kumar, Subrata Maji, Pronab Kundu, Uttam K. Ghorai, Rajendra P. Giri, Bidisa Das, Nitin Chattopadhyay, Binay K. Ghorai, Somobrata Acharya
ACS APPLIED MATERIALS & INTERFACES
(2018)
Article
Chemistry, Multidisciplinary
Kuheli Mandal, Debabrata Jana, Binay K. Ghorai, Nikhil R. Jana
NEW JOURNAL OF CHEMISTRY
(2018)
Article
Chemistry, Multidisciplinary
Shatabdi Boxi, Debabrata Jana, Partha P. Parui, Binay K. Ghorai
Article
Chemistry, Inorganic & Nuclear
Pramita Mondal, Sandip Biswas, Debabrata Jana, Bidisa Das, Uttam K. Ghorai, Binay K. Ghorai, Somobrata Acharya
JOURNAL OF SOLID STATE CHEMISTRY
(2020)
Article
Chemistry, Multidisciplinary
Nirmalendu Biswas, Sachinath Bera, Nayim Sepay, Amrita Pal, Tanmoy Halder, Sudipta Ray, Swarnali Acharyya, Anup Kumar Biswas, Michael G. B. Drew, Tapas Ghosh
NEW JOURNAL OF CHEMISTRY
(2020)
Article
Chemistry, Multidisciplinary
Nirmalendu Biswas, Sachinath Bera, Nayim Sepay, Titas Kumar Mukhopadhyay, Krishnendu Acharya, Sandipta Ghosh, Swarnali Acharyya, Anup Kumar Biswas, Michael G. B. Drew, Tapas Ghosh
NEW JOURNAL OF CHEMISTRY
(2019)
Article
Nanoscience & Nanotechnology
Kuheli Mandal, Debabrata Jana, Binay K. Ghorai, Nikhil R. Jana
ACS APPLIED NANO MATERIALS
(2019)
Article
Chemistry, Inorganic & Nuclear
Debashis Patra, Subhabrata Paul, Indira Majumder, Nayim Sepay, Sachinath Bera, Rita Kundu, Michael G. B. Drew, Tapas Ghosh
DALTON TRANSACTIONS
(2017)
Article
Chemistry, Inorganic & Nuclear
Nirmalendu Biswas, Debashis Patra, Bipul Mondal, Sachinath Bera, Swarnali Acharyya, Anup Kumar Biswas, Titas Kumar Mukhopadhyay, Amrita Pal, Michael G. B. Drew, Tapas Ghosh
DALTON TRANSACTIONS
(2017)
Article
Chemistry, Organic
Geeta Devi Yadav, Pooja Chaudhary, Balaram Pani, Surendra Singh
Summary: Chiral transition metal complexes with privileged ligands are efficient catalysts for various asymmetric organic transformations. Transition metal complexes of C1-symmetric pyrrolidine-based ligands have been widely used in asymmetric organic reactions. However, a comprehensive review article on the transition metal complexes of chiral C1-symmetric pyrrolidine-based ligands derived from (L)-proline has not been published.
TETRAHEDRON LETTERS
(2024)
