期刊
TETRAHEDRON LETTERS
卷 53, 期 13, 页码 1660-1663出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2012.01.086
关键词
Heck-Matsuda; Pentabromopseudilin; Arylpyrrole
资金
- Brazilian National Research Council (CNPq)
- Research Supporting Foundation of the State of Sao Paulo (FAPESP)
Pentrabromopseudilin and other 2 and 3-arylpyrrole derivatives were synthesized through the Heck-Matsuda reaction involving endocyclic enecarbamates and N-protected 3-pyrrolines, respectively. The overall processes permitted an easy and efficient access to these structural motifs present in several bioactive compounds. Attempts to synthesize the compound isopentabromopseudilin led to a tribromo aryl maleimide. We hypothesize that this latter compound is the putative product arising from the unusual thermal instability of isopentabromopseudilin. (C) 2012 Elsevier Ltd. All rights reserved.
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