Review
Chemistry, Multidisciplinary
Biplob Borah, Kartikey Dhar Dwivedi, Bhupender Kumar, L. Raju Chowhan
Summary: Significant progress has been made in the synthesis of coumarins and bioactive heterocycles. The utilization of non-conventional methods such as microwave and ultrasound-assisted strategies has propelled the development in this field.
ARABIAN JOURNAL OF CHEMISTRY
(2022)
Article
Biochemistry & Molecular Biology
Manuel Velasco, Nancy Romero-Ceronio, Rosalia Torralba, Oswaldo Hernandez Abreu, Miguel A. Vilchis-Reyes, Erika Alarcon-Matus, Erika M. Ramos-Rivera, David M. Aparicio, Jacqueline Jimenez, Eric Aguilar Garcia, David Cruz Cruz, Clarisa Villegas Gomez, Cuauhtemoc Alvarado
Summary: The study presents a simple and efficient method for the synthesis of coumarin-3-carboxamides, using a metal-free and clean reaction system with low catalyst loading and no tedious workup.
Article
Engineering, Environmental
Marina Godino-Ojer, Sergio Morales-Torres, Elena Perez-Mayoral, Francisco J. Maldonado-Hodar
Summary: A highly efficient method for selectively synthesizing nitrogen heterocycles using carbon-supported ZnO catalysts under green chemistry conditions is presented. The physicochemical properties of different carbon supports play a role in catalytic performance. The developed catalysts, prepared by simple impregnation and thermal treatment, show great performance in the selective synthesis of quinolines under mild conditions.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2022)
Article
Chemistry, Multidisciplinary
Mohammad Hosein Sayahi, Fatemeh Shamkhani, Mohammad Mahdavi, Saeed Bahadorikhalili
Summary: This paper presents an efficient method for the synthesis of 10-methyl-7-aryl-7,12-dihydro-6H,8H-chromeno[4,3-b]pyrano[3,4-e]pyridine-6,8-dione derivatives in water using non-toxic catalyst L-proline. The method avoids the use of any toxic solvent and shows promise for green chemistry practices.
RESEARCH ON CHEMICAL INTERMEDIATES
(2021)
Article
Chemistry, Multidisciplinary
Yong Tang, Kaifu Zhang, Yuelin Xu, Jinglin Ma, Hanqing Xie, Hongquan Zhang, Yanmin Jiang, Rui Zhao, Lei Wang
Summary: A green and efficient method for the construction of functionalized 2,3-dihydrothiophene derivatives in water was reported. Novozym 435 demonstrated remarkable catalytic activity in the four-component reaction of aldehydes, malonitrile or ethyl cyanoacetate, 1,3-thiazolidinedione, and amines, resulting in excellent product yields. Furthermore, the catalyst could be reused for multiple cycles.
NEW JOURNAL OF CHEMISTRY
(2023)
Article
Chemistry, Organic
Baofu Zhu, Jiaming He, Kai Zou, Anquan Li, Chen Zhang, Jiaji Zhao, Hua Cao
Summary: This study established a three-component reaction catalyzed by base, involving ynals, isocyanates, amines, and alcohols. The strategy enables a wide range of substrates and provides a simple process for the preparation of diverse pyridine derivatives with good yields and high regioselectivities.
JOURNAL OF ORGANIC CHEMISTRY
(2023)
Article
Chemistry, Applied
Dong Li, Zhishuang Wang, Hualin Zhang, Ningyi Lu, Lei Cui, Ningmin Wu, Chunju Li, Jian Li
Summary: We present a multicomponent reaction based on isocyanide that allows the assembly of various tricyclic chromenopyrrole derivatives with diastereoselectivity. By utilizing phenol as an electron-rich species, this protocol achieves diverse structures through a bicyclization process.
ADVANCED SYNTHESIS & CATALYSIS
(2022)
Article
Chemistry, Multidisciplinary
Huan Liu, Zi-Lin Ye, Zhong-Jian Cai, Shun-Jun Ji
Summary: In this study, a novel, efficient and metal-free multicomponent reaction of isocyanides, selenium powder and 3-aminooxetanes was reported. The reaction used selenium powder as the selenium source and H2O as the sole reaction medium, resulting in a series of 1,3-selenazolines under mild conditions. The transformation demonstrated good functional group compatibility, broad substrate scope and high atom economy, while avoiding the use of unstable and toxic selenium agents, additional phase transfer catalysts and transition-metal catalysts, aligning with the concept of green organic synthesis. Additionally, the obtained selenazolines were easily applied to the derivatization of biologically active molecules, providing a new avenue for the synthesis of drug-like organoselenium compounds.
Article
Chemistry, Physical
Muhammad Ismail, Maria Rasheed, Chandreswar Mahata, Myounggon Kang, Sungjun Kim
Summary: A nano-crystalline ZnO-based memristor was fabricated to investigate the short-term memory characteristics in reservoir computing systems. The NC-ZnO-based memristor exhibited remarkable endurance and had a high to low resistance ratio of 102. It displayed long data retention and consistent resistive switching, showing excellent performance characteristics. By controlling pulse parameters, short-term synaptic plasticity was effectively replicated, and an artificial neural network achieved high pattern recognition accuracy. NC-ZnO-based memristor has immense potential in constructing high-performance neuromorphic computing systems.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Chemistry, Applied
Fabio Wilbert, Thomas J. J. Mueller
Summary: A novel consecutive three-component Heck-condensation sequence was applied to synthesize a series of 3-arylallylidene indolones with variable substitutions as diastereomeric mixtures in a one-pot synthesis approach. The N-substitution pattern was found to be crucial for the fluorescence behavior in the solid state. The structure-property relationship was studied by extending the synthetic route to generate a diverse compound library of Boc-substituted 3-arylallylidene indolones, revealing discontinuous behavior of the longest wavelength absorption bands of these compounds.
Article
Chemistry, Multidisciplinary
Vishal Singh, Khushbu Rajput, Pratibha Verma, Sundaram Singh, Vandana Srivastava
Summary: The present study developed a new one-pot synthesis method for 2-oxo-1,2,3,4-tetrahydropyrimidines. This method employed methyl arenes as a substitute for aldehydes, in situ generation of urea, and eco-friendly lactic acid as a green catalyst to achieve solvent-free synthesis of the desired product via the Biginelli reaction. The method showcased environmentally friendly mild reaction conditions, easily accessible and cost-effective starting materials, a valuable bio-based green catalyst, aerobic conditions, short reaction time, tolerance towards various functional groups, and easy isolation of the final product with high yield even without the use of chromatographic separation technique.
RESEARCH ON CHEMICAL INTERMEDIATES
(2023)
Article
Chemistry, Multidisciplinary
Bikash Karmakar, Rajesh Nandi
Summary: The functionalized mesoporous silica nanoparticle promoted synthesis of 2-amino-4H-chromenes from phenolic components, different aldehydes, and malononitrile in aqueous media at room temperature. The method offers advantages of short reaction times, environmentally friendly conditions, high yields, and operational convenience. The catalyst can be reused multiple times without significant loss in activity.
RESEARCH ON CHEMICAL INTERMEDIATES
(2021)
Article
Chemistry, Applied
Laurent Remy, Guillaume Sudre, Aurelia Charlot, Etienne Fleury
Summary: This work presents a Passerini modification of carboxymethyl cellulose (CMC) using a library of nine α-substituted ketone derivatives and cyclohexyl isocyanide. The Passerini ligation, carried out in aqueous and mild conditions, successfully produces eco-friendly dually functionalized CMC derivatives. The study investigates various experimental parameters, such as stoichiometry, co-solvent nature, and temperature, to control the extent of modification. The resulting Passerini CMC products are further modified with methacrylate moieties and used for grafting through copolymerization, leading to thermoresponsive hydrogels with potential applications in drug delivery, dye removal, and actuation.
CARBOHYDRATE POLYMERS
(2023)
Article
Multidisciplinary Sciences
Azra Ghiasi Moaser, Ahmad Gholami Afkham, Roushan Khoshnavazi, Sadegh Rostamnia
Summary: Three nickel substituted Keggin-type polyoxometalates (SiW9Ni3) were selectively intercalated into Zn3Al based Layered Double Hydroxide (Zn3Al-LDH) using ion-exchange technique. The resulting nanocomposite, SiW9Ni3@Zn3Al, acted as a heterogeneous nanoreactor for the synthesis of drug-like aminoimidazopyridine small molecules via Ugi-type Groebke-Blackburn-Bienayme reaction (GBB 3-CRs) without any acid/additive under mild and solvent-free conditions. The catalytic property of SiW9Ni3@Zn3Al was enhanced compared to the individual components, indicating a synergistic catalytic effect between SiW9Ni3 polyoxometalate and Zn3Al-LDH precursors. The Lewis/Bronsted acidity of SiW9Ni3 polyoxometalate and Zn3Al-LDH precursors played essential roles in the catalytic performance of the composite.
SCIENTIFIC REPORTS
(2023)
Article
Chemistry, Applied
H. A. Duarte, P. J. Luggren, J. Zelin, M. E. Sad, V. K. Diez, J. I. Di Cosimo
Summary: The selective synthesis of benzaldehyde (B) from benzyl alcohol (BA) using ZnOMnCO3 catalysts was investigated. The catalytic activity of the materials depended on the loading of Zn, and the most promising catalyst achieved a maximum benzaldehyde yield of 88%. The synergistic contribution of Zn and Mn species played a crucial role in the catalytic activity.
Article
Chemistry, Multidisciplinary
Prasun Mukherjee, Sanjay Paul, Asish R. Das
NEW JOURNAL OF CHEMISTRY
(2015)
Article
Chemistry, Multidisciplinary
Nazia Kausar, Partha Pratim Ghosh, Gargi Pal, Asish R. Das
Article
Chemistry, Organic
Prasun Mukherjee, Asish R. Das
JOURNAL OF ORGANIC CHEMISTRY
(2016)
Article
Chemistry, Multidisciplinary
Prasun Mukherjee, Asish R. Das
Article
Chemistry, Applied
Sanjay Paul, Koyel Pradhan, Sirshendu Ghosh, S. K. De, Asish R. Das
ADVANCED SYNTHESIS & CATALYSIS
(2014)
Article
Chemistry, Multidisciplinary
Koyel Pradhan, Sanjay Paul, Asish R. Das
MONATSHEFTE FUR CHEMIE
(2014)
Article
Chemistry, Organic
Sanjay Paul, Koyel Pradhan, Sirshendu Ghosh, S. K. De, Asish R. Das
Article
Chemistry, Physical
Koyel Pradhan, Sanjay Paul, Asish R. Das
CATALYSIS SCIENCE & TECHNOLOGY
(2014)
Article
Chemistry, Multidisciplinary
Gargi Pal, Sanjay Paul, Partha Pratim Ghosh, Asish R. Das
Article
Chemistry, Multidisciplinary
Indranil Roy, Amartya Bhattacharyya, Gunjan Sarkar, Nayan Ranjan Saha, Dipak Rana, Partha Pratim Ghosh, Mainak Palit, Asish Ranjan Das, Dipankar Chattopadhyay
Article
Chemistry, Multidisciplinary
Moumita Saha, Koyel Pradhan, Asish R. Das
Article
Chemistry, Multidisciplinary
Nazia Kausar, Indranil Roy, Dipankar Chattopadhyay, Asish R. Das
Article
Chemistry, Organic
Geeta Devi Yadav, Pooja Chaudhary, Balaram Pani, Surendra Singh
Summary: Chiral transition metal complexes with privileged ligands are efficient catalysts for various asymmetric organic transformations. Transition metal complexes of C1-symmetric pyrrolidine-based ligands have been widely used in asymmetric organic reactions. However, a comprehensive review article on the transition metal complexes of chiral C1-symmetric pyrrolidine-based ligands derived from (L)-proline has not been published.
TETRAHEDRON LETTERS
(2024)