期刊
TETRAHEDRON LETTERS
卷 53, 期 38, 页码 5088-5093出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2012.07.023
关键词
Palladium; Weinreb amides; Arylation; Chelation
资金
- Basic Science Research Program through the National Research Foundation of Korea (NRF)
- Ministry of Education, Science, and Technology [2012R1A1B3000541]
Palladium-catalyzed arylation of alpha,beta-unsaturated Weinreb amides has been examined to obtain beta-aryl-alpha,beta-unsaturated Weinreb amides. The chelation between the palladium center of an alkylpalladium intermediate and Weinreb amide moiety facilitated both coordination and insertion steps. (C) 2012 Elsevier Ltd. All rights reserved.
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