期刊
TETRAHEDRON LETTERS
卷 53, 期 38, 页码 5131-5135出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2012.07.051
关键词
Arenes; Benzylation; Electrophilic aromatic substitution; Mitsunobu reaction; Phosphorus
资金
- Razi University
Triphenylphosphine ditriflate (TPPD) was found to be an efficient promoter for the Friedel-Crafts benzylation of arenes with benzyl alcohols in CH2Cl2 at room temperature. The good yields, the 1:1 molar ratio of arene and benzyl alcohol, the benzylation of chlorobenzene as a nonactivated aromatic compound at room temperature, and no by-product formation are the main advantages of this procedure. (C) 2012 Elsevier Ltd. All rights reserved.
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