期刊
TETRAHEDRON LETTERS
卷 53, 期 51, 页码 6995-6998出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2012.10.064
关键词
Sodium benzotriazolide; Iridium; Phosphoramidite ligand; Asymmetric allylation
资金
- Pu Jiang Program of Shanghai
- NSFC [21272175]
A highly enantioselective allylic substitution of sodium benzotriazolide has been attained in the presence of [Ir(COD)Cl](2)/phosphoramidite ligand L1 together with K3PO4 as an additive, producing enantioen-riched allylbenzotriazole compounds with up to 98% ee. (C) 2012 Elsevier Ltd. All rights reserved.
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