期刊
TETRAHEDRON LETTERS
卷 52, 期 45, 页码 6003-6006出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2011.08.167
关键词
Pyrrolidines; Nitrones; Dipolar cycloaddition; Nucleoside analogues; Peptide nucleic acids
资金
- Spanish Ministry of Science and Innovation (MICINN Madrid, Spain) [CTQ2010-19606]
- FEDER
- Government of Aragon (Group E-10, Zaragoza, Spain)
- MIUR (Italy)
- CNMPS (Italy)
- MICINN
- University of Palermo
Two monomers for the syntheses of conformationally restricted peptide nucleic acids were synthesized through a simple procedure, involving an asymmetric 1,3-dipolar cycloaddition chemistry as a key step, from common starting materials in 3 and 5 steps, and 58.8% and 30.5% overall yields, respectively. (C) 2011 Elsevier Ltd. All rights reserved.
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