期刊
TETRAHEDRON LETTERS
卷 52, 期 24, 页码 3133-3136出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2011.04.029
关键词
Reduction; Indium; Silane; Ether; Alcohol
资金
- Japan Private School Promotion Foundation
- MEXT
- Grants-in-Aid for Scientific Research [21590025] Funding Source: KAKEN
An InBr3-Et3SiH reducing system was developed to selectively convert aliphatic ketones to a variety of secondary alcohols in moderate to good yields. An initial mixing of InBr3 and PhSiH3 was followed by the addition of aliphatic ketones and a solvent to afford the symmetrical ether derivatives. (C) 2011 Elsevier Ltd. All rights reserved.
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