期刊
TETRAHEDRON LETTERS
卷 51, 期 19, 页码 2636-2638出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2010.03.026
关键词
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资金
- Petroleum Research Fund (PRF) [43238-AC1]
- American Chemical Society
- Bryn Mawr College
- Irena Bronstein-Bonte Fellowship
A new extension of the Birch-Cope sequence is described which allows the efficient enantioselective construction of highly functionalized, fused bicarbocyclic structures with an all-carbon quaternary stereo-center in two steps. The two-step sequence includes a cross metathesis between a terminal alkene and a polarized alkene followed by an intramolecular Rauhut-Currier reaction with a trialkylphosphine catalyst. (C) 2010 Elsevier Ltd. All rights reserved.
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